Detail of "7559-36-6"
- CAS Number:
- 7559-36-6
- Name:
Benzene,1-methyl-4-(2-nitroethenyl)-
- Molecular Structure:
- Formula:
- C9H9 N O2
- Synonyms:
- Styrene,p-methyl-b-nitro- (6CI,7CI,8CI);1-Methyl-4-(2-nitroethenyl)benzene; 1-Methyl-4-(2-nitrovinyl)benzene;2-(4-Methylphenyl)-1-nitroethene; 4-(2-Nitroethenyl)toluene;4-(2-Nitrovinyl)toluene; 4-Methyl-b-nitrostyrene; 4-Methyl-w-nitrostyrene; p-(2-Nitrovinyl)toluene; p-Methyl-b-nitrostyrene;p-Methylnitrostyrene; b-Nitro-4-methylstyrene
Benzene,1-methyl-4-(2-nitroethenyl)-
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Reference
- Anionic polymerization of b-nitrostyrenes
- Anionic polymerization of b-nitrostyrenes. Berry, Robert W. H.; Mazza, Robert J.; Sullivan, Stuart F. (Dep. Sci., Mid-Kent Coll. Higher Further Educ., Chatham/Kent, UK). Makromol. Chem., 185(3), 559-67 (English) 1984. CODEN: MACEAK. ISSN: 0025-116X. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) The rate of polymn. of b-nitrostyrene [102-96-5] initiated by Na alkoxides was studied gravimetrically. The rate was first order with respect to monomer concn. and first order with respect to initiator concn. Rate consts. in the order of 0.25 dm3.mol-1.s-1 were obtained at 15, 20, and 25° for the polymn. of b-nitrostyrene, p-methoxy-b-nitrostyrene [3179-10-0], and p-methyl-b-nitrostyrene [7559-36-6] initiated by NaOMe [124-41-4] and by NaOEt [141-52-6]. The activation energies of polymns. initiated by NaOMe and NaOEt were ~24 and ~16 kJ.mol-1, resp. The no.-av. d.p. of poly(b-nitrosytrene)s was detd. by polymn. of the monomer in the presence of 14C-alkanol. Previously, accurate no.-av. mol. wts. could not be reported since conventional methods of mol. wt. detn. could not be used owing to the insoly. of these polymers in most common org.Except for chemicals metioned above, 7559-36-6 and 141-52-6 are also used. solvents. .
- Acid hydrolysis of derivatives of N-(2'-nitroethoxy)-3-cyano-3-nitroisoxazolidine
- Acid hydrolysis of derivatives of N-(2'-nitroethoxy)-3-cyano-3-nitroisoxazolidine. Zheved, T. D.; Altukhov, K. V. (Leningr. Gos. Pedagog. Inst. im. Gertsena, Leningrad, USSR). Zh. 99-94-5 and 7559-36-6 are cas registry numbers of chemicals which are used as reagents here. Org. Khim., 12(9), 2028-30 (Russian) 1976. CODEN: ZORKAE. DOCUMENT TYPE: Journal CA Section: 28 (Heterocyclic Compounds (More Than One Hetero Atom)) Hydrolysis of I (R = H, Me) by HCl gave p-RC6H4CH:CHCO2H and small amts. of p-RC6H4CO2H. Similar hydrolysis with AcOH gave 58 and 75% intermediate II (R = H, Me) which were easily hydrolyzed by HCl to give the corresponding cinnamic and benzoic acids. .