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| CAS No.: | 76578-14-8 |
|---|---|
| Name: | Quizalofop-ethyl |
| Article Data: | 6 |
| Molecular Structure: | |
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| Formula: | C19H17 Cl N2 O4 |
| Molecular Weight: | 372.808 |
| Synonyms: | Assure; DPX6202; DPX-Y 6202; DPX-Y 6202-3; Ethyl 2-[4-(6-chloro-2-quinoxalyloxy)phenoxy]propionate;Miura; NC 302; NCI 96683; Quinofop-ethyl; Quizalofop-ethyl; Targa;Xylofop-ethyl |
| Density: | 1.301 g/cm3 |
| Melting Point: | 91.7-92.1oC |
| Boiling Point: | 503.9 °C at 760 mmHg |
| Flash Point: | 258.6 °C |
| Solubility: | 303ug/L(temperature not stated) |
| Hazard Symbols: | R21/22:; |
| Risk Codes: | R21/22 |
| Safety: | Moderately toxic by ingestion, skin contact, and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NOx and Cl−. |
| PSA: | 70.54000 |
| LogP: | 4.40590 |
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Chemistry
IUPAC Name: Ethyl 2-[4-(6-chloroquinoxalin-2-yl)oxyphenoxy]propanoate
Synonyms: 2-[4-[(6-Chloro-2-quinoxalinyl)oxy]phenoxy]Propanoic Acid Ethyl Ester ; 2-{4-[(6-Chloro-2-quinoxalinyl)oxy]phénoxy}propanoate d'éthyle ; DPX Y6202 ; Ethyl 2-{4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy}propanoate ; Ethyl 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoate ; Ethyl-2-{4-[(6-chlorchinoxalin-2-yl)oxy]phenoxy}propanoat ; Propanoic acid, 2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]-, ethyl ester ; Quizalofop-ethyl
Molecular Structure: 
Molecular Formula : C19H17ClN2O4
Molecular Weight : 372.80
CAS NO: 76578-14-8
Merck : 13,8178
Index of Refraction: 1.604
Surface Tension: 50.7 dyne/cm
Density: 1.301 g/cm3
Flash Point: 258.6 °C
Enthalpy of Vaporization: 77.33 kJ/mol
Boiling Point: 503.9 °C at 760 mmHg
Vapour Pressure: 2.78E-10 mmHg at 25°C
Storage temp: 0-6°C
Appearance: Quinofop-ethyl (CAS NO.76578-14-8) is white crystals.
Solubility : Quinofop-ethyl (CAS NO.76578-14-8) is insoluble in water.
Uses
Quinofop-ethyl (CAS NO.76578-14-8) is used as bud post-emergence herbicide in dry land .primarily control grass weeds for soybeans, peanuts, cotton, potatoes, green beans, watermelon, canola and other broadleaf crops.
Toxicity Data With Reference
| 1. | orl-rat LD50:1480 mg/kg | 85JFAN “Agrochemicals Handbook“, with updates, Hartley, D., and H. Kidd, eds., Nottingham, UK, Royal Soc. of Chemistry, 1983-86 A541 ,1985. | ||
| 2. | skn-rat LD50:1852 mg/kg | DOVEAA Defense des Vegetaux. 40 (240)(1986),17. | ||
| 3. | ipr-rat LD50:2510 mg/kg | NNGADV Nippon Noyaku Gakkaishi. 16 (1991),315. | ||
| 4. | scu-rat LD50:>10 g/kg | JPIFAN Japan Pesticide Information.(48)(1986),13. | ||
| 5. | orl-mus LD50:2350 mg/kg | 85JFAN “Agrochemicals Handbook“, with updates, Hartley, D., and H. Kidd, eds., Nottingham, UK, Royal Soc. of Chemistry, 1983-86 A541 ,1985. | ||
| 6. | skn-mus LD50:10 g/kg | 85JFAN “Agrochemicals Handbook“, with updates, Hartley, D., and H. Kidd, eds., Nottingham, UK, Royal Soc. of Chemistry, 1983-86 A541 ,1985. | ||
| 7. | ipr-mus LD50:641 mg/kg | NNGADV Nippon Noyaku Gakkaishi. 16 (1991),315. | ||
| 8. | scu-mus LD50:>10 g/kg | JPIFAN Japan Pesticide Information.(48)(1986),13. |
Safety Profile
Moderately toxic by ingestion, skin contact, and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NOx and Cl−.
Hazard Codes 
Xn
Risk Statements 21/22
R21/22:Harmful in contact with skin and if swallowed.
Safety Statements 22-24/25
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
RIDADR UN3077 9/PG 3
RTECS UA2458255
Specification
Reactivity Profile: A halogenated ester and amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.