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7704-99-6

Basic Information
CAS No.: 7704-99-6
Name: ZIRCONIUM HYDRIDE
Molecular Structure:
Molecular Structure of 7704-99-6 (ZIRCONIUM HYDRIDE)
Formula: H2Zr
Molecular Weight: 93.23 .
Synonyms: Zirconiumdihydride; Zirconium hydride
EINECS: 231-727-3
Density: 5.6 g/cm3 (20ºC)
Melting Point: 1857oC
Boiling Point: °Cat760mmHg
Flash Point: None flammable
Solubility: Insoluble
Appearance: gray-black powder
Hazard Symbols: 4.1 UN NO.
Risk Codes: 11-36/37/38
Transport Information: 143
PSA: 0.00000
LogP: 0.00000
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Chemistry

Product Name: Zirconium hydride (CAS NO.7704-99-6)


Molecular Formula: H2Zr
Molecular Weight: 93.24g/mol
Mol File: 7704-99-6.mol
Einecs: 231-727-3
Appearance: Gray-black powder
Melting Point: 800°C (decomposes)
Density: 5.60 g/cm3
Water Solubility: Insoluble
Sensitive: Moisture Sensitive
H-Bond Donor: 0
H-Bond Acceptor: 0
Heavy Atom Count: 1
Product Categories: Catalysis and Inorganic Chemistry; Materials for Hydrogen Storage; Metal HydridesAlternative Energy; Metal HydridesChemical Synthesis; Reduction; Synthetic Reagents; Zirconium

Uses

 Zirconium hydride (CAS NO.7704-99-6) is used in powder metallurgy, as a hydrogenation catalyst, and as a reducing agent, vacuum tube getter, and a foaming agent in production of metal foams. It is also used as a neutron moderator in thermal-spectrum nuclear reactors such as the TRIGA research reactor developed by General Atomics or the Soviet TOPAZ nuclear reactors. Other uses include acting as a fuel in pyrotechnic compositions, namely pyrotechnic initiators.

Toxicity Data With Reference

1.    

itr-rat TDLo:45 g/kg/26W-I

    GISAAA    Gigiena i Sanitariya. 37 (7)(1972),36.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of Zirconium hydride (CAS NO.7704-99-6):
Hazard Codes: F
Risk Statements: 11-36/37/38 
11:  Highly Flammable
36:  Irritating to the eyes 
37:  Irritating to the respiratory system 
38:  Irritating to the skin 
Safety Statements: 24/25-43-7/8
7:  Keep container tightly closed 
8:  Keep container dry 
24:  Avoid contact with skin 
25:  Avoid contact with eyes 
43:  In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)

Standards and Recommendations

OSHA PEL: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3
ACGIH TLV: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3; Not Classifiable as a Human Carcinogen
DFG MAK: 1 mg(Zr)/m3
DOT Classification:  4.1; Label: Flammable Solid

Specification

 Zirconium hydride ,its CAS NO. is 7704-99-6,the synonyms is Zirconium dihydride ; Zirconium(ii) bydride ; Zirconium(ii) hydride ; Dihydridezirconium(ii) ; Dihydrogen zirconium(ii) salt .