Detail of "7726-97-8"

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610 Integral
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910 Integral
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C-Glycosides and C-nucleosides: C-Glycosides and C-nucleosides. I. Synthesis of 2,3-0-isopropylidene-a,D-erythrofuranosyl C-glycosides and C-nucleosides. Lopez Herrera, F. J.; Gomez Perez, C.; Valpuesta Fernandez, M. (Dep. Quim.Some commonly used reagents like 7726-97-8 is used in this experiment. Org., Univ. Malaga, Spain). An. Quim., Ser. C, 80(3), 218-23 (Spanish) 1984. CODEN: AQSBD6. ISSN: 0211-1357. DOCUMENT TYPE: Journal CA Section: 33 (Carbohydrates) Section cross-reference(s): 22 Reaction of anhydroarabinose I (R = CHO) with R1O2CCH2CO2H (R1 = Me, Et) or N2CHCO2Me gave the corresponding C-glycosides (I; R = trans-CH:CHCO2R1, COCH2CO2Me) in 93, 71, and 63% yield, resp. The reaction of these C-glycosides with urea and its derivs. gave pyrimidine C-nucleosides, e.g., II. Conformational anal. of these C-glycosides and C-nucleosides by 1H-NMR confirmed the a-anomeric configuration. .