CAS No.7782-61-8,Ferric nitrate nonahydrate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	7782-61-8
Name:	Ferric nitrate nonahydrate
Article Data:	29

Formula:	FeH₁₈N₃O₁₈
Molecular Weight:	241.862
Synonyms:	Nitric acid, iron(3+)salt, nonahydrate (9CI);Iron nitrate (Fe(NO3)3) nonahydrate;Iron trinitratenonahydrate;Iron(3+) nitrate nonahydrate;Iron(III) nitrate nonahydrate;UNII-VMX4UOP3VN;
EINECS:	233-899-5
Density:	1.68 g/cm³
Melting Point:	47.2 °C(lit.)
Boiling Point:	125 °C
Flash Point:	125 °C
Solubility:	soluble in water; soluble in alcohol, acetone
Appearance:	pale purple solid
Hazard Symbols:	O,Xi
Risk Codes:	8-36/37/38
Safety:	17-26-36-24/25
Transport Information:	UN 1466 5.1/PG 3
PSA:	289.71000
LogP:	0.27110

Synthetic route

: (CH3)3SiCHCH2(SFe(CO)3)2

: 7697-37-2
nitric acid

A: 7782-61-8
ferric nitrate

B: 754-05-2
ethenyltrimethylsilane

Conditions

Conditions	Yield
In nitric acid byproducts: H2SO4, NO, CO; stirring for 0.5 h at 25°C; condensing silane in a trap cooled with solid CO2, treating aq. layer with NaOH, evapn. to dryness, IR;	A n/a B 99%

...Expand

: (CH3)2Si(CH2CHSFe(CO)3)2

: 7697-37-2
nitric acid

A: 16054-12-9
1,1-Dimethylsilacyclopent-3-en

B: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
In nitric acid byproducts: H2SO4, NO, CO; stirring for 0.5 h at 25°C; condensing silane in a trap cooled with solid CO2, treating aq. layer with NaOH, evapn. to dryness, IR;	A 96% B n/a

...Expand

: iron(III) oxide

: 7697-37-2
nitric acid

: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
In water dissolving of Fe2O3 in excess of HNO3 for 30 - 45 days; not isolated, measuring of conc. of Fe(3+) by photometrically;

: 7697-37-2
nitric acid

: 7439-89-6
iron

: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
In nitric acid Fe is dissolved in dild. HNO3 with evolution of gas, formation of Fe(NO3)3;;
In nitric acid byproducts: basic iron(III)nitrate; Fe is dissolved in HNO3 (d = 1.115), formation of Fe(NO3)3 and basic iron(III)nitrate;;
In nitric acid byproducts: basic iron(III)nitrate; aq. HNO3; Fe is dissolved in HNO3 (d = 1.115), formation of Fe(NO3)3 and basic iron(III)nitrate;;
In nitric acid aq. HNO3; Fe is dissolved in dild. HNO3 with evolution of gas, formation of Fe(NO3)3;;
In ethanol; water for 24h;

: 7697-37-2
nitric acid

: 7439-89-6
iron

A: iron(II) nitrate

B: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
In nitric acid storing of Fe for a longer period of time in fuming HNO3;;
In nitric acid storing of Fe for a longer period of time in fuming HNO3;;

...Expand

: 7697-37-2
nitric acid

: 7439-89-6
iron

A: iron(II) nitrate

B: ammonium nitrate

C: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
In nitric acid Fe is dissolved in HNO3 (d = 1.073), formation of a mixture of Fe(NO3)2 Fe(NO3)3 and NH4NO3;;
In nitric acid aq. HNO3; Fe is dissolved in HNO3 (d = 1.073), formation of a mixture of Fe(NO3)2 Fe(NO3)3 and NH4NO3;;

...Expand

: 7697-37-2
nitric acid

: 7439-89-6
iron

A: 7664-41-7
ammonia

B: 10102-44-0
Nitrogen dioxide

C: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
In nitric acid Fe is dissolved in HNO3 (34%, d =1.21), at the beginning Fe is dissolved quickly with evolution of gas, then slowly without evolution of gas and formation of Fe(NO3)3 and traces of NO2 and NH3;;
In nitric acid aq. HNO3; Fe is dissolved in HNO3 (34%, d =1.21), at the beginning Fe is dissolved quickly with evolution of gas, then slowly without evolution of gas and formation of Fe(NO3)3 and traces of NO2 and NH3;;

...Expand

: iron(III) sulfate

: ammonium hydroxide

: 7697-37-2
nitric acid

A: Ammonium

B: 14808-79-8
Sulfate

C: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
In water addn. of 10 % soln. of NH4OH to soln. of Fe-salt (pptn.), filtration, washing (hot water) to remove NH4(1+), and SO4(2-), redissolving of Fe(OH)3 in 0.5 M HNO3;

...Expand

: 13463-40-6
iron pentacarbonyl

: 7697-37-2
nitric acid

A: iron(II) nitrate

B: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
In tetrachloromethane byproducts: CO, H2, nitrogen oxides;
In diethyl ether byproducts: CO, H2, nitrogen oxides;

...Expand

: 7439-89-6
iron

: 7782-61-8
ferric nitrate

Conditions

Conditions	Yield
With nitric acid In nitric acid dissoln. of Fe in HNO3 (d > 1.115); formation of Fe(NO3)3 and basic iron nitrates;;
With nitric acid In nitric acid byproducts: HNO2; dissoln. of Fe in a 20-fold excess of HNO3 at 8°C; first formation of Fe(NO3)2, which is oxidized by formed HNO2 to Fe(NO3)3;;
With nitric acid In nitric acid dissoln. of Fe in HNO3 (d = 1.115); formation of Fe(NO3)3;;

Raw Materials

Downstream Products

764-60-3

Total:106 Page 1 of 3 1 2 3 Next>>

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Chemistry

Molecular Structure of Ferric nitrate nonahydrate (CAS NO.7782-61-8):

IUPAC Name: Iron(3+) trinitrate nonahydrate
Molecular Formula: FeH₁₈N₃O₁₈
Molecular Weight: 403.99722 g/mol
Density: 1.68 g/cm³
Melting Point: 47 °C(lit.)
Boiling Point: 125°C
Flash Point: 125°C
Storage Temp.: store at RT.
Water Solubility: soluble
H-Bond Donor: 9
H-Bond Acceptor: 18
Exact Mass: 403.993478
MonoIsotopic Mass: 403.993478
Topological Polar Surface Area: 208
Heavy Atom Count: 22
Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.O.O.O.[Fe+3]
InChI: InChI=1S/Fe.3NO3.9H2O/c;3*2-1(3)4;;;;;;;;;/h;;;;9*1H2/q+3;3*-1;;;;;;;;;
InChIKey: SZQUEWJRBJDHSM-UHFFFAOYSA-N
EINECS: 233-899-5

Uses

Ferric nitrate nonahydrate (CAS NO.7782-61-8) is used as catalyst, dye mordant, metal surface conditioning agent, oxidant, analytical reagent and radiomaterial sorbent. It also can be used in the research and development of medicine.

Production

Ferric nitrate nonahydrate is prepared by treating iron metal or iron oxides with nitric acid.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	oral	3250mg/kg (3250mg/kg)		American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.

Safety Profile

Hazard Codes: Oxidizing O, Irritant Xi
Risk Statements: 8-36/37/38
R8: Contact with combustible material may cause fire.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 17-26-36-24/25
S17: Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
S24/25: Avoid contact with skin and eyes.
RIDADR: UN 1466 5.1/PG 3
WGK Germany: 1
RTECS: NO7175000
F: 3-9-23
HazardClass: 5.1
PackingGroup: III
HS Code: 28342980
Moderately toxic by ingestion.

Standards and Recommendations

OSHA PEL: TWA 1 mg(Fe)/m³
ACGIH TLV: TWA 1 mg(Fe)/m³

Specification

Ferric nitrate nonahydrate (CAS NO.7782-61-8) also can be called for Iron(+3)nitrate enneahydrate ; Iron(III) nitrate ; Iron(III) nitrate-9-hydrate ; Iron(III) nitrate enneahydrate ; Iron(III) nitrate,hydrous ; Iron(III) nitrate nonahydrate ; Iron(III) nitrate,nonohydrate . Ferric nitrate nonahydrate (CAS NO.7782-61-8) is a strong oxidizer and it may lead to fire when contact with combustible material. It's incompatible with combustible material, strong reducing agents, most common metals, organic material. Ferric nitrate nonahydrate is a pale purple solid and it's stable under normal shipping and handling conditions. However, it may decompose if heated. May discolor on exposure to light. After decomposition, Ferric nitrate nonahydrate turned into nitrogen oxides , irritating and toxic fumes and gases.When heated to decomposition it emits toxic fumes of NO_x.