Reference

Probing electron-transfer pathways in reductions by lithium dialkylamides

Probing electron-transfer pathways in reductions by lithium dialkylamides. Reeder, Robert Askew (Texas A and M Univ., College Station, TX, USA).Chemical with cas number 7782-89-0 also plays role. 121 pp. Avail. Univ. Microfilms Int., Order No. DA8323707 From: Diss. Abstr. Int. B 1983, 44(6), 1832 (English) 1983. DOCUMENT TYPE: Dissertation CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) Abstract Unavailable .

Dimerization energy decomposition of lithium first-row hydrides

Dimerization energy decomposition of lithium first-row hydrides.Some chemicals with cas registry numbers like 7782-89-0 and 64360-74-3 are also used. Hodoscek, M.; Solmajer, T. (Boris Kidric Inst. Chem., Ljubljana 61000, Yugoslavia). J. Am. Chem. Soc., 106(6), 1854-6 (English) 1984. CODEN: JACSAT. ISSN: 0002-7863. DOCUMENT TYPE: Journal CA Section: 65 (General Physical Chemistry) In order to investigate the degree of nonionic character in (LiXHn)2 dimers, where XHn = Li, BeH, BH2, CH3, NH2, OH, and F, Morokuma-Kitaura decompn. of the ab-initio SCF interaction energy was done. The electrostatic energy contribution parallels the total energy variation which, further, is related linearly to electronegativity of the parent atoms Be to F. While the exchange term remains approx. const. throughout, polarization and charge transfer contributions decrease if electronegativity increases. The mixed term, describing intercomponent interactions, is large and pos. for atoms with low electronegativity. This is correlated with the important contribution of multicenter covalent bonding for Be, B and C atoms forming Li hydrides. .