Reference

Synthesis and Multinuclear NMR Study of Benzoyl Methylene Tri-para-tolylphosphorane Ylide and the Reaction of this Ylide with Mercury(II) Halides

All Rights Reserved. Synthesis and Multinuclear NMR Study of Benzoyl Methylene Tri-para-tolylphosphorane Ylide and the Reaction of this Ylide with Mercury(II) Halides. Sabounchei, Seyyed; Dadrass, A.; Samiee, Sepideh (Chemistry Department, Bu-Ali-Sina University, Hamadan, Iran). Phosphorus, Sulfur and Silicon and the Related Elements, 181(6), 1331-1337 (English) 2006 Taylor & Francis, Inc. CODEN: PSSLEC. ISSN: 1042-6507. 917814-30-3 and 7783-34-8 are cas registry numbers of chemicals which are used as reagents here. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 22 The reaction of the title ylide {PhCOCHP(p-tolyl)3} with Pd(II), Pt(II), Hg(II) and Ag(I) in equimolar ratios using MeCN, MeOH, and CH2Cl2 as solvents have yielded [{(p-tolyl)3PCHCOC6H5}×PdCl2]2 (1), [{(p-tolyl)3 PCHCOC6H5}×PtCl2]2 (2), [Hg(NO3)2 {(p-tolyl)3 PCHCOC6H5}] (3) and [Ag{(p-tolyl)3 PCHCOC6H5}2]+ (4). The IR, 1H 13C, and 31P NMR together with micro anal. data of the products were obtained and indicates one type of mol. for the complexes as expected for metal-carbon coordination of the ylide. .