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7783-40-6

Basic Information
CAS No.: 7783-40-6
Name: Magnesium fluoride
Article Data: 122
Molecular Structure:
Molecular Structure of 7783-40-6 (Magnesium fluoride)
Formula: MgF2
Molecular Weight: 62.3018
Synonyms: Magnesium fluorure [French];Irtran 1;magnesium(+2) cation difluoride;Afluon;Magnesium fluoride (MgF2);Sellaite;Aluminum Chlorohydrate Solution;Magnesium fluoride, powder;Magnesium fluoride(MgF2);
EINECS: 231-995-1
Density: 3.15 g/mL at 25 °C(lit.)
Melting Point: 1248 °C
Boiling Point: 19.5 °C at 760 mmHg
Solubility: 87 mg/L (18 °C ) in water
Appearance: white to light beige powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36-37/39
PSA: 0.00000
LogP: 0.84040
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    Magnesium fluoride CAS 7783-40-6

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Chemistry

Molecular Structure of Magnesium fluoride (CAS NO.7783-40-6):

IUPAC Name: magnesium difluoride
Molecular Formula: F2Mg
Molecular Weight: 62.31
EINECS: 231-995-1
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: 0Å2
Melting Point: 1248oC
Enthalpy of Vaporization: 25.54 kJ/mol
Boiling Point: 19.5 °C at 760 mmHg
Vapour Pressure: 922 mmHg at 25°C
Water Solubility: 87 mg/L (18oC)
Merck: 14,5665 
InChI
InChI=1/2FH.Mg/h2*1H;/q;;+2/p-2
Smiles
[Mg](F)F
Product Categories: Inorganics; Magnesium; Crystal Grade Inorganics; Inorganic Salts; Magnesium Salts; MagnesiumMetal and Ceramic Science; Salts;Synthetic Reagents

Production

  Magnesium fluoride (CAS NO.7783-40-6) has the production. Magnesium carbonate method: in lead lined reactor containing an excessive amount of hydrofluoric acid, in the stirring join the slurry magnesite at 90 ~ 95 ℃ under the reaction. The reaction of magnesium fluoride, followed by filtration, washing, drying at 105 ℃ or so, and then by crushing, magnesium fluoride can obtain the product.
MgCO3 +2HF → MgF2 + H2O + C02

Toxicity Data With Reference

1.    

orl-gpg LDLo:1 g/kg

    MEIEDD    Merck Index. 11 (1989),892.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of F. See also MAGNESIUM and FLUORIDES.
Safety Information of Magnesium fluoride (CAS NO.7783-40-6):
Hazard Codes: IrritantXi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany: 3
RTECS: OM3325000
Hazard Note: Irritant
HS Code: 28261900

Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: TWA 2.5 mg(F)/m3

Specification

  Magnesium fluoride , with CAS number of 7783-40-6, can be called Afluon ; Irtran 1 ; Sellaite ; Cyanamide,cyano-,magnesium salt ; magnesium(+2) cation difluoride ; Aluminum Chlorohydrate Solution . It is a white to light beige powder, Magnesium fluoride (CAS NO.7783-40-6) can be used as flux for smelting magnesium, aluminum additives, optical lens coatings, titanium pigment painted agents, cathode-ray screen of fluorescent material, etc.