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7784-16-9

Basic Information
CAS No.: 7784-16-9
Name: SODIUM TETRACHLOROALUMINATE
Article Data: 22
Molecular Structure:
Molecular Structure of 7784-16-9 (SODIUM TETRACHLOROALUMINATE)
Formula: AlCl4Na
Molecular Weight: 191.783
Synonyms: Sodium tetrachloroaluminate;
EINECS: 232-050-6
Density: 2.01 g/mL at 25 °C(lit.)
Melting Point: 185 °C(lit.)
Solubility: Soluble in water
Hazard Symbols: CorrosiveC
Risk Codes: 14-34
Safety: 22-26-27-36/37/39-45
PSA: 0.00000
LogP: 2.75800
Synthetic route
7647-14-5

sodium chloride

7784-16-9

sodium tetrachloroaluminate

Conditions
ConditionsYield
With aluminium trichloride
With hydrogenchloride; aluminum oxide In melt melt of NaCl in graphite crucible; Al2O3 tube affected;
7446-70-0

aluminium trichloride

A

7784-16-9

sodium tetrachloroaluminate

B

7429-90-5

aluminium

Conditions
ConditionsYield
With sodium In neat (no solvent) passing excess AlCl3 vapor over Na in a iron tube at 200-300°C;completion of the reaction by heating the mixture of Al and NaAlCl3 in pots of clay or cast iron until beginning vaporization of NaAlCl3;; removal and melting of Al balls;;
With Na In neat (no solvent) passing excess AlCl3 vapor over Na in a iron tube at 200-300°C;completion of the reaction by heating the mixture of Al and NaAlCl3 in pots of clay or cast iron until beginning vaporization of NaAlCl3;; removal and melting of Al balls;;
7429-90-5

aluminium

7647-14-5

sodium chloride

7784-16-9

sodium tetrachloroaluminate

Conditions
ConditionsYield
In not given
7446-70-0

aluminium trichloride

7647-14-5

sodium chloride

7784-16-9

sodium tetrachloroaluminate

Conditions
ConditionsYield
In neat (no solvent) drybox and vac. line techniques; fused together in an ampoule; recrystd., decanted, zone-refining;
pre-electrolysis and filtration;
In neat (no solvent, solid phase) stoich. quant. of AlCl3 and NaCl (previously fused at 1023 K) were fused together under Ar;
7446-70-0

aluminium trichloride

7784-16-9

sodium tetrachloroaluminate

Conditions
ConditionsYield
With NaCl In melt AlCl3/NaCl melt (170-240°C), NaCl satd.;
10026-04-7, 53609-55-5

tetrachlorosilane

NaY zeolite

A

7784-16-9

sodium tetrachloroaluminate

B

Na2(AlO2)2(SiO2)190

Conditions
ConditionsYield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 450°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;
10026-04-7, 53609-55-5

tetrachlorosilane

NaY zeolite

A

7784-16-9

sodium tetrachloroaluminate

B

Na5(AlO2)5(SiO2)187

Conditions
ConditionsYield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 375°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;
10026-04-7, 53609-55-5

tetrachlorosilane

NaY zeolite

A

7784-16-9

sodium tetrachloroaluminate

B

Na24(AlO2)24(SiO2)168

Conditions
ConditionsYield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 300°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;
10026-04-7, 53609-55-5

tetrachlorosilane

NaY zeolite

A

7784-16-9

sodium tetrachloroaluminate

B

Na20(AlO2)20(SiO2)172

Conditions
ConditionsYield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 350°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;
10026-04-7, 53609-55-5

tetrachlorosilane

NaY zeolite

A

7784-16-9

sodium tetrachloroaluminate

B

Na26(AlO2)26(SiO2)166

Conditions
ConditionsYield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 250°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;
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Specification

The Aluminium sodium tetrachloride is an organic compound with the formula AlCl4Na. The IUPAC name of this chemical is sodium tetrachloroalumanuide. With the CAS registry number 7784-16-9, the product's categories are AluminumMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; Salts; Sodium Salts. Besides, it should be stored in a closed cool and dry place.

When you are using this chemical, please be cautious about it as the following:
It reacts violently with water. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical can cause burns. When you are using it, wear suitable gloves and eye/face protection and do not breathe dust. Please take off immediately all contaminated clothing. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].Cl[Al-](Cl)(Cl)Cl
(2)InChI: InChI=1/Al.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4/rAlCl4.Na/c2-1(3,4)5;/q-1;+1
(3)InChIKey: CMLRNXGMTZKKSR-MLBQZSPTAH
(4)Std. InChI: InChI=1S/Al.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4
(5)Std. InChIKey: CMLRNXGMTZKKSR-UHFFFAOYSA-J