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CAS No.: | 7784-16-9 |
---|---|
Name: | SODIUM TETRACHLOROALUMINATE |
Article Data: | 22 |
Molecular Structure: | |
Formula: | AlCl4Na |
Molecular Weight: | 191.783 |
Synonyms: | Sodium tetrachloroaluminate; |
EINECS: | 232-050-6 |
Density: | 2.01 g/mL at 25 °C(lit.) |
Melting Point: | 185 °C(lit.) |
Solubility: | Soluble in water |
Hazard Symbols: | C |
Risk Codes: | 14-34 |
Safety: | 22-26-27-36/37/39-45 |
PSA: | 0.00000 |
LogP: | 2.75800 |
Conditions | Yield |
---|---|
With aluminium trichloride | |
With hydrogenchloride; aluminum oxide In melt melt of NaCl in graphite crucible; Al2O3 tube affected; |
Conditions | Yield |
---|---|
With sodium In neat (no solvent) passing excess AlCl3 vapor over Na in a iron tube at 200-300°C;completion of the reaction by heating the mixture of Al and NaAlCl3 in pots of clay or cast iron until beginning vaporization of NaAlCl3;; removal and melting of Al balls;; | |
With Na In neat (no solvent) passing excess AlCl3 vapor over Na in a iron tube at 200-300°C;completion of the reaction by heating the mixture of Al and NaAlCl3 in pots of clay or cast iron until beginning vaporization of NaAlCl3;; removal and melting of Al balls;; |
Conditions | Yield |
---|---|
In not given |
Conditions | Yield |
---|---|
In neat (no solvent) drybox and vac. line techniques; fused together in an ampoule; recrystd., decanted, zone-refining; | |
pre-electrolysis and filtration; | |
In neat (no solvent, solid phase) stoich. quant. of AlCl3 and NaCl (previously fused at 1023 K) were fused together under Ar; |
Conditions | Yield |
---|---|
With NaCl In melt AlCl3/NaCl melt (170-240°C), NaCl satd.; |
tetrachlorosilane
A
sodium tetrachloroaluminate
Conditions | Yield |
---|---|
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 450°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.; |
tetrachlorosilane
A
sodium tetrachloroaluminate
Conditions | Yield |
---|---|
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 375°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.; |
tetrachlorosilane
A
sodium tetrachloroaluminate
Conditions | Yield |
---|---|
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 300°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.; |
tetrachlorosilane
A
sodium tetrachloroaluminate
Conditions | Yield |
---|---|
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 350°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.; |
tetrachlorosilane
A
sodium tetrachloroaluminate
Conditions | Yield |
---|---|
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 250°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.; |
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The Aluminium sodium tetrachloride is an organic compound with the formula AlCl4Na. The IUPAC name of this chemical is sodium tetrachloroalumanuide. With the CAS registry number 7784-16-9, the product's categories are AluminumMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; Salts; Sodium Salts. Besides, it should be stored in a closed cool and dry place.
When you are using this chemical, please be cautious about it as the following:
It reacts violently with water. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical can cause burns. When you are using it, wear suitable gloves and eye/face protection and do not breathe dust. Please take off immediately all contaminated clothing. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].Cl[Al-](Cl)(Cl)Cl
(2)InChI: InChI=1/Al.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4/rAlCl4.Na/c2-1(3,4)5;/q-1;+1
(3)InChIKey: CMLRNXGMTZKKSR-MLBQZSPTAH
(4)Std. InChI: InChI=1S/Al.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4
(5)Std. InChIKey: CMLRNXGMTZKKSR-UHFFFAOYSA-J