CAS No.7790-86-5,CERAMICS-AEium(III) chloride Suppliers,MSDS download

Products Categories

Pharmaceutical (76)
Others (28)
Organic Chemicals (26)
Reagent (8)
Materials (7)
Basic Inorganic Chemicals (6)
Plant Extract (3)
Catalyst and Auxiliary (1)
Synthetic Flavours & Fragrances (1)

Basic Information

Molecular Structure:
CAS No.:	7790-86-5
Name:	CERAMICS-AEium(III) chloride
Article Data:	96

Formula:	CeCl₃
Molecular Weight:	246.479
Synonyms:	Cerium trichloride;Cerium chloride (CeCl3);Cerous chloride;Cerous(III) chloride;
EINECS:	232-227-8
Density:	3.97 g/mL at 25 °C(lit.)
Melting Point:	848 °C(lit.)
Boiling Point:	1727 °C
Flash Point:	1727°C
Appearance:	white powder
Hazard Symbols:	Xi
Risk Codes:	36/37/38
Safety:	26-36
PSA:	0.00000
LogP:	-8.98800

Synthetic route

: ([Ce(μ-Cl)(H2O)7](Cl)2)2

: 7790-86-5
cerium chloride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: H2O; Schlenk techniques; heating Ce compd. under vacuum (1E-3 Torr);	99%

: cerium(III) sulfate pentahydrate

: ammonium chloride

: 7790-86-5
cerium chloride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: H2O, NH3; a mixt. of Ce-contg. compd. and NH4Cl (2.5-fold excess) was gradually heated to 830°C under He for 12 h; chem. anal.;	96.4%

: cerium(IV) oxide

: 7790-86-5
cerium chloride

Conditions

Conditions	Yield
With HCl In hydrogenchloride; formic acid (N2 or Ar); stirring the mixt. of CeO2, HCl (37 %) and HCOOH under reflux for 24 h;; evapn. of the soln. to dryness; dehydration of the remaining solid under vacuum (0.01 mm Hg) at ca. 170°C; for 48 h; elem. anal.;;	96%
With complex compd. of PCl5 and AlCl3 according to: L. A. Nisel'son, Yu. N. Lyzlov, K. V. Tret'yakova, Zh. Neorg. Khim.20 (1975) 2362; elem. anal., X-ray diffraction;
In not given

: cerium(IV) oxide

: aluminium chloride dimer

A: aluminum oxochloride

B: 7790-86-5
cerium chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Cl2; Al2Cl6 prepd. from Al and Cl2; in Duran tube, at 500°C (Cl2); chemical vapour phase transport with Al2Cl6 from 500 to 400°C, 24 h;	A n/a B 41%

...Expand

: 177723-35-2, 64332-99-6
[CeCl3(H2O)]

: 917-54-4
methyllithium

A: 34557-54-5
methane

B: 7790-86-5
cerium chloride

C: 1310-65-2
lithium hydroxide

Conditions

Conditions	Yield
In tetrahydrofuran (vac.);	A 40% B n/a C n/a

...Expand

: cerium(III) chloride heptahydrate

: ammonium chloride

: 7790-86-5
cerium chloride

Conditions

Conditions	Yield
In neat (no solvent) absence of moisture; large excess NH4Cl, evacuated quartz tube, 500-600 K; sublimation off of excess NH4Cl (vac., 700 K);

cerium chloride monohydrate: cerium chloride monohydrate

: 7790-86-5
cerium chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2O; sample heating at 120-140°C until weight loss reached the calculated value; gravimetric monitoring;

: cerium(III) chloride hydrate

: 7790-86-5
cerium chloride

Conditions

Conditions	Yield
With ammonium chloride In neat (no solvent) byproducts: H2O; mixing CeCl3*99H2O with an excess of NH4Cl, firing at 500°C for 1 h in a H2 atmosphere;
With NH4Cl Taylor M.D., Carter C.P., J. Inorg. Nucl. Chem. 1962, 24, 387;

: cerium(III) oxide

: potassium chloride

A: 7790-86-5
cerium chloride

B: potassium oxide

Conditions

Conditions	Yield
In melt 1100°C;
In melt 1100°C;

...Expand

: 75-44-5
phosgene

: cerium(III) oxide

: 7790-86-5
cerium chloride

Conditions

Conditions	Yield
In neat (no solvent) passing stream of COCl2 over Ce2O3 at 600 °C;;

Raw Materials

917-54-4

Downstream Products

537-00-8

Total:122 Page 1 of 4 1 2 3 4 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 7790-86-5

Specification

The Cerium chloride, with the CAS registry number 7790-86-5, is also known as Cerous chloride. It belongs to the product categories of Inorganics; Ce (Cerium) Compounds; Classes of Metal Compounds; Transition Metal Compounds; Metal Halide. Its EINECS registry number is 232-227-8. This chemical's molecular formula is CeCl₃ and molecular weight is 246.48. What's more, its systematic name is called Cerium(3+) trichloride. It can be made by dehydration of the hydrate either by slowly heating to 400 °C with 4-6 equivalents of ammonium chloride under high vacuum, or by heating with an excess of thionyl chloride for three hours. Cerium(III) chloride can be used as a starting point for the preparation of other cerium salts, such as the Lewis acid, cerium(III) trifluoromethanesulfonate, used for Friedel-Crafts acylations. It is also used itself as a Lewis acid, for example as a catalyst in Friedel-Crafts alkylation reactions.

Physical properties about Cerium chloride are: (1)Density: 3.97 g/cm³; (2)Flash Point: 1727 °C; (3)Melting point: 848 °C(lit.); (4)Boiling Point: 1727 °C at 760 mmHg.

Uses of Cerium chloride: it is used to produce other chemicals. For example, it can react with sodium borohydride to get allylic alcohol.

Cerium chloride can react with sodium borohydride to get allylic alcohol.

When you are dealing with this chemical, you should be very careful. This chemical is inflammation to the skin, eyes and respiratory system or other mucous membranes. Therefore, you should wear suitable protective clothing. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: [Cl-].[Cl-].[Cl-].[Ce+3]
(2) InChI: InChI=1S/Ce.3ClH/h;3*1H/q+3;;;/p-3
(3) InChIKey: VYLVYHXQOHJDJL-UHFFFAOYSA-K

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
dog	LDLo	intravenous	60mg/kg (60mg/kg)		"Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
frog	LD50	subcutaneous	211mg/kg (211mg/kg)		Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
guinea pig	LD50	intraperitoneal	104mg/kg (104mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: ANOREXIA (HUMAN BEHAVIORAL: MUSCLE WEAKNESS	AMA Archives of Industrial Health. Vol. 15, Pg. 9, 1957.
mouse	LD50	intraperitoneal	97849ug/kg (97.849mg/kg)		Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
mouse	LD50	oral	5277mg/kg (5277mg/kg)		Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
mouse	LDLo	subcutaneous	4gm/kg (4000mg/kg)		Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 188, Pg. 465, 1938.
rat	LD50	intravenous	6262ug/kg (6.262mg/kg)	LIVER: "HEPATITIS (HEPATOCELLULAR NECROSIS), DIFFUSE"	Acta Physiologica Polonica. Vol. 32, Pg. 205, 1981.
rat	LD50	oral	2111mg/kg (2111mg/kg)		Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat	LDLo	subcutaneous	4gm/kg (4000mg/kg)	BEHAVIORAL: TREMOR BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 100, Pg. 230, 1923.