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78-75-1

Basic Information
CAS No.: 78-75-1
Name: 1,2-Dibromopropane
Article Data: 93
Molecular Structure:
Molecular Structure of 78-75-1 (1,2-Dibromopropane)
Formula: C3H6Br2
Molecular Weight: 201.889
Synonyms: 2,3-Dibromopropane;Propylene dibromide;
EINECS: 201-139-1
Density: 1.926 g/cm3
Melting Point: -55 °C
Boiling Point: 140.4 °C at 760 mmHg
Flash Point: 21.9 °C
Solubility: slightly soluble in water
Appearance: Colorless liquid
Hazard Symbols: HarmfulXn
Risk Codes: 10-20/22-36/37/38-20/21/22
Safety: 23-24/25-36/37/39-26-16
Transport Information: UN 1993 3/PG 3
PSA: 0.00000
LogP: 2.16470
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  • 78-75-1            C3H6Br2             1,2-Dibromopropane

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Chemistry

Molecular Formula: C3H6Br2
Formula Weight: 201.89
IUPAC Name: 1,2-Dibromopropane
Synonyms: 1,2-Propylenebromide ; 2-Bromopropylbromide ; (RS)-Dibrompropan ; Propane,1,2-dibromo- ; 1,2-Propylene Dibromide
Melting Point: -55 °C
Boiling Point: 140-142 °C(lit.)
Density of 2,3-Dibromopropane (78-75-1): 1.937 g/mL at 25 °C(lit.)
Refractive index : n20/D 1.519(lit.)
Flash Point: 35 °
Storage temp.: Flammables area
Water Solubility: 2,3-Dibromopropane (78-75-1) is slightly soluble
Chemical Properties: 2,3-Dibromopropane (78-75-1) is a colorless liquid.
Stability: 2,3-Dibromopropane (78-75-1) is stable. Flammable. Incompatible with strong oxidizing agents, strong bases, magnesium.

Uses

 2,3-Dibromopropane (78-75-1) is used as an intermediate, raw material, chemical reagent and solvent in organic synthesis.

Production

1. 2,3-Dibromopropane (78-75-1) is formed from propylene by direct bromination.
2. It is derived from bromopropane by bromination.
3. Propanol bromide method

Toxicity Data With Reference

1.    

sln-dmg-orl 5 mmol/L

    EXPEAM    Experientia. 30 (1974),621.
2.    

orl-rat LD50:741 mg/kg

    GISAAA    Gigiena i Sanitariya. 41 (3)(1976),105.
3.    

ihl-rat LC50:12 g/m3/4H

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,43.
4.    

orl-mus LD50:676 mg/kg

    GISAAA    Gigiena i Sanitariya. 41 (3)(1976),105.
5.    

ipr-mus LD50:75 mg/kg

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD691-490 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of Br. See also PROPANE and BROMIDES.
Safety: DANGER: FLAMMABLE, irritates skin, eyes, lungs
Hazard Codes : Xn: Harmful
Risk Statements : 10: Flammable
20/22: Harmful by inhalation and if swallowed
36/37/38: Irritating to eyes, respiratory system and skin
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements : 23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24/25: Avoid contact with skin and eyes
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
16: Keep away from sources of ignition - No smoking 
RIDADR : UN 1993 3/PG 3
WGK Germany : 3
RTECS : TX8574000
HazardClass : 3
PackingGroup : III
HS Code : 29033036

Standards and Recommendations

ASSAY: 98.0% MIN
WATER: 0.1% max

Specification

 2,3-Dibromopropane (78-75-1) is a colorless liquid slightly soluble in water (miscible with organic solvents). It is stable under ordinary conditions and mainly used as a intermediate for the synthesis of pharmaceuticals and other organic compounds. 2,3-Dibromopropane (78-75-1) is considered non-flammable.