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Basic Information
CAS No.: 79-78-7
Name: ALLYL IONONE
Molecular Structure:
Molecular Structure of 79-78-7 (ALLYL IONONE)
Formula: C16H24 O
Molecular Weight: 232.40
Synonyms: 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-one;Allyl-a-ionone; Cetone V
EINECS: 201-225-9
Density: 0.928 g/mL at 25 °C(lit.)
Boiling Point: 313.4 °C at 760 mmHg
Flash Point: 137.6 °C
Solubility: soluble in alcohol; insoluble in water
Appearance: colourless to yellow liquid with a fruity, woody odour
Safety: A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS.
PSA: 17.07000
LogP: 4.46040
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Chemistry

Product Name: Allyl α-ionone (CAS NO.79-78-7)


Molecular Formula: C16H24O
Molecular Weight: 232.36g/mol
Mol File: 79-78-7.mol
Einecs: 201-225-9
Appearance: Colourless to yellow liquid with a fruity, woody odour
Boiling point: 313.4 °C at 760 mmHg
Flash Point: 137.6 °C
Density: 0.928 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.505(lit.)
Solubility: Soluble in alcohol; insoluble in water
Surface Tension: 33.3 dyne/cm
Enthalpy of Vaporization: 55.45 kJ/mol
Vapour Pressure: 0.000498 mmHg at 25°C
XLogP3-AA: 4
H-Bond Donor: 0
H-Bond Acceptor: 1
Product Categories: A-B; Alphabetical Listings; Flavors and Fragrances

Uses

GB 2760 - 1996: provisions allowing the use of food with the spices. Allyl α-ionone (CAS NO.79-78-7) is mainly used for preparation of pineapple and other fruit-type flavor.

Production

The presence of sodium in methanol, Allyl α-ionone (CAS NO.79-78-7) is a lemon condensation of aldehydes with allyl acetone first, and then boron trifluoride catalyzed cyclization formed.

Toxicity Data With Reference

1.    

skn-rbt 500 mg MLD

    FCTXAV    Food and Cosmetics Toxicology. 11 (1973),1079.
2.    

skn-rbt LD50:>5 g/kg

    FCTXAV    Food and Cosmetics Toxicology. 11 (1973),493.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS.

Specification

 Allyl α-ionone ,its CAS NO. is 79-78-7,the synonyms is 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-one ; 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-6-heptadien-3-one ; 6-Heptadien-3-one,1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1 ; Allylalpha-ionon ; 1-(2,6,6-Trimethylcyclohex-2-enyl)hepta-1,6-dien-3-one ; Allyl ionone ; Allyl alpha-ionone ; (e)-1-(2,6,6-Trimethyl-cyclohex-2-enyl)-hepta-1,6-dien-3-one .