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| CAS No.: | 80-52-4 |
|---|---|
| Name: | 1,8-DIAMINO-P-MENTHANE |
| Article Data: | 10 |
| Molecular Structure: | |
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| Formula: | C10H22 N2 |
| Molecular Weight: | 170.298 |
| Synonyms: | p-Menthane-1,8-diamine(7CI,8CI); 1,8-Diamino-p-menthane; 1,8-Menthanediamine; 1,8-p-Menthanediamine;1-Amino-1-methyl-4-(2-amino-2-propyl)cyclohexane;1-Methyl-4-(1-amino-1-methylethyl)cyclohexylamine; Menthanediamine; NSC 5612;Primene MD |
| EINECS: | 201-287-7 |
| Density: | 0.914 g/mL at 25 °C(lit.) |
| Melting Point: | ?45 °C(lit.) |
| Boiling Point: | 107-126 °C10 mm Hg(lit.) |
| Flash Point: | 200 °F |
| Appearance: | dark coloured liquid |
| Hazard Symbols: | Strong irritant to eyes and skin, calls for eye protection. |
| Risk Codes: | 23/24/25-34 |
| Safety: | Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits toxic fumes of NOx. See also AMINES. |
| Transport Information: | UN 2922 8 |
| PSA: | 52.04000 |
| LogP: | 3.03190 |
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Chemistry
MF: C10H22N2
MW: 170.3
EINECS: 201-287-7
Flash Point: 200 °F
Melting Point: −45 °C(lit.)
Density: 0.914 g/mL at 25 °C(lit.)
Vapor pressure: 10 mm Hg ( 20 °C)
Refractive index: n20/D 1.4805(lit.)
Appearance: dark coloured liquid
Boiling Point: 246.5 °C at 760 mmHg
IUPAC Name: 4-(2-Aminopropan-2-yl)-1-methylcyclohexan-1-amine
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
Synonyms: 4-(1-Amino-1-methylethyl)-1-methylcyclohexanamine ; 4-Amino-.alpha.,.alpha.-4-trimethyl-Cyclohexanemethanamine ; 4-Amino-alpha,alpha,4-trimethylcyclohexanemethamine ; 4-Amino-alpha,alpha,4-trimethyl-cyclohexanemethanamin ; Ai3-23799 ; Menthanediamine ; NSC5612 ; P-Menthane-1,8-diamine
Following is the molecular structure of P-Menthane-1,8-diamine (80-52-4):
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Production
Reactivity Profile: -Menthane-1,8-diamine (80-52-4): neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Toxicity Data With Reference
| 1. | skn-rbt 100 µg/24H open | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
| 2. | orl-rat LD50:770 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470. | ||
| 3. | ipr-mus LD50:50 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) No. AD277-689 . | ||
| 4. | skn-rbt LD50:292 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by skin contact and intraperitoneal routes. Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits toxic fumes of NOx
Safety Information of P-Menthane-1,8-diamine (80-52-4):
Hazard Codes: T .gif){kind=small}
Risk Statements: 23/24/25-34
23/24/25: Toxic by inhalation, in contact with skin and if swallowed
34: Causes burns
Safety Statements: 26-27-28-36/37/39-45
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27: Take off immediately all contaminated clothing
28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR: UN 2922 8/PG 2
WGK Germany: 3
RTECS: OS8925000
HazardClass: 8
PackingGroup III