CAS No.84-65-1,Anthraquinone Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	84-65-1
Name:	Anthraquinone
Article Data:	560

Formula:	C₁₄H₈O₂
Molecular Weight:	208.216
Synonyms:	EPA Pesticide Chemical Code 122701;Hoelite;Morkit;Anthraquinone [BSI:ISO];9,10-Anthraquinone;9,10-Dioxoanthracene;Anthracene, 9,10-dihydro-9,10-dioxo-;Corbit;Anthradione;Bis-alkylamino anthraquinone;Anthrapel;9,10-Anthrachinon [Czech];9.10-Anthraquinone;anthra-9,10-quinone;anthracene-9,10-dione;Anthraquinone(AQ);
EINECS:	201-549-0
Density:	1.308 g/cm³
Melting Point:	284-286 °C(lit.)
Boiling Point:	377 °C at 760 mmHg
Flash Point:	141.4 °C
Solubility:	water: <0.1 g/100 mL at 23 °C
Appearance:	dull yellow powder
Hazard Symbols:	Xi
Risk Codes:	43-36/37/38
Safety:	36/37-37/39-26-24
PSA:	34.14000
LogP:	2.46200

Synthetic route

: 613-31-0
9,10-dihydroanthracene

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With oxygen In acetone at 20℃; under 760.051 Torr; for 10h; Reagent/catalyst; Solvent; Irradiation;	100%
With [bis(acetoxy)iodo]benzene; tert-butyl hydroxyperoxide; 3-chloro-benzenecarboperoxoic acid In 2,2,2-trifluoroethanol at 20℃; for 9h;	99%
With 2-Picolinic acid; manganese(II) perchlorate hexahydrate; dihydrogen peroxide; sodium acetate In acetonitrile at 0 - 20℃;	99%

: 120-12-7
anthracene

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With nicotinium dichromate In acetic acid for 0.75h; Heating;	100%
With potassium bromate In acetic acid Heating;	100%
With ruthenium trichloride; dihydrogen peroxide; acetic acid	100%

: 90-44-8
anthracen-9(10H)-one

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With aluminum oxide; potassium permanganate; water In 1,2-dichloro-ethane for 75h; Ambient temperature;	100%
With aluminum oxide; potassium permanganate for 75h;	100%
With cerium(III) sulfate; barium bromate In water; acetonitrile for 20h; Heating;	97%

: 58343-58-1
9,10-dihydro-9,10-dihydroxyanthracene

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 0.0333333h; Microwave irradiation;	100%
With tert.-butylhydroperoxide; RhCl(PPh3)3 In benzene at 70℃; for 48h;	87%
With tert.-butylhydroperoxide; RhCl(PPh3)3 In benzene at 70℃; for 48h;	87%

: 9-methylsulfinyl-10-(methylthio)anthracene

A: 624-92-0
Dimethyldisulphide

B: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
Stage #1: 9-methylsulfinyl-10-(methylthio)anthracene With air; sulfuric acid In dichloromethane at 20℃; for 0.0833333h; Rearrangement; Stage #2: With water; sodium hydrogencarbonate Hydrolysis;	A n/a B 100%

: 1-anthracen-9-yl-ethane-1,2-diol

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With osmium(VIII) oxide; trimethylamine-N-oxide In tetrahydrofuran; pyridine; water at 65℃;	100%

: 100622-34-2
anthracene-9-boronic acid

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With water; sodium hydroxide In tetrahydrofuran at 20℃; for 2h; Reagent/catalyst;	99.03%

: 2395-97-3
9,10-dimethoxyanthracene

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With zinc(II) nitrate; silica gel In tetrachloromethane for 0.25h; Heating;	98%
With hydrogenchloride; iodosylbenzene for 0.0833333h; Oxidation;	79%
With air; acetic acid Irradiation;
With bromine
With iodine

: 2444-68-0
9-vinylanthracene

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With aluminum oxide; potassium permanganate In dichloromethane at 20℃; for 72h;	98%

: 106-99-0
buta-1,3-diene

: 123-31-9
hydroquinone

: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With oxygen; pyrographite In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 120℃; under 760.051 Torr; for 48h; Schlenk technique; Cooling with ice;	98%

Downstream Products

82-48-4

3071-34-9

1572-99-2

613-31-0

79-91-4

118-90-1

632-83-7

1055-23-8

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Chemistry

Molecular Structure of Anthraquinone (CAS NO.84-65-1):

Molecular Formula: C₁₄H₈O₂
Molecular Weight: 208.2121
IUPAC Name: Anthracene-9,10-dione
Synonyms of Anthraquinone (CAS NO.84-65-1): Anthraquinone [BSI:ISO] ; 9,10-Anthracenedione ; 9,10-Anthrachinon ; 9,10-Anthrachinon [Czech] ; 9,10-Anthraquinone ; 9,10-Dioxoanthracene ; AI3-09073 ; Anthracene, 9,10-dihydro-9,10-dioxo- ; Bis-alkylamino anthraquinone ; CCRIS 649 ; Caswell No. 052A ; Corbit ; EINECS 201-549-0 ; EPA Pesticide Chemical Code 122701 ; HSDB 2074 ; Hoelite ; Morkit ; NSC 7957
CAS NO: 84-65-1
Classification Code: Agricultural Chemical ; Avicide ; Mutation data ; TSCA Flag T [Subject to the Section 4 test rule under TSCA] ; Tumor data
Melting Point: 284-286 °C
Index of Refraction: 1.659
Molar Refractivity: 58.66 cm³
Molar Volume: 159 cm³
Surface Tension: 55.8 dyne/cm
Density: 1.308 g/cm³
Flash Point: 141.4 °C
Enthalpy of Vaporization: 62.47 kJ/mol
Boiling Point: 377 °C at 760 mmHg
Vapour Pressure: 6.97E-06 mmHg at 25°C

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
mouse	LD50	oral	> 5gm/kg (5000mg/kg)	Pesticide Manual. Vol. 9, Pg. 37, 1991.
quail	LD50	unreported	> 2gm/kg (2000mg/kg)	Farm Chemicals Handbook. Vol. -, Pg. C23, 1991.
rat	LC50	inhalation	> 1300mg/m3/4H (1300mg/m3)	Pesticide Manual. Vol. 9, Pg. 37, 1991.
rat	LD50	intraperitoneal	3500mg/kg (3500mg/kg)	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(12), Pg. 27, 1977.
rat	LD50	skin	> 1gm/kg (1000mg/kg)	"Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A019, Pg. 1983,
rat	LDLo	oral	15gm/kg (15000mg/kg)	"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 22, 1982.

Consensus Reports

Anthraquinone (CAS NO.84-65-1) is reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes of Anthraquinone (CAS NO.84-65-1): Irritant Xi
Risk Statements: 43-36/37/38
R43: May cause sensitization by skin contact.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 36/37-39-26-24
S36/37: Wear suitable protective clothing and gloves.
S39: Wear eye / face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24: Avoid contact with skin.
WGK Germany: 1
RTECS: CB4725000

Specification

1. Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
2. Handling and Storage
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.