Detail of "87-62-7"

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CAS Number:
87-62-7
Name:
Benzenamine,2,6-dimethyl-
Superlist Name:
2,6-Dimethylaniline
Molecular Structure:
Formula:
C₈H₁₁N
Molecular Weight:
121.18
Synonyms:
2,6-Xylidine(8CI);1-Amino-2,6-dimethylbenzene;2,6-Dimethylbenzenamine;2,6-Dimethylphenylamine;2,6-Xylylamine;2-Amino-1,3-dimethylbenzene;2-Amino-1,3-xylene;2-Amino-m-xylene;NSC 7098;o-Xylidine;2,6 Xylidine;
EINECS:
201-758-7
Density:
0.975 g/cm³
Melting Point:
10-12 °C(lit.)
Boiling Point:
217.9 °C at 760 mmHg
Flash Point:
91.1 °C
Solubility:
water: 7.5 g/L (20 °C)
Appearance:
colorless to reddish yellow liquid
Hazard Symbols:
Xn,N,T
Risk Codes:
20/21/22-37/38-40-51/53
Safety:
23-25-36/37-61 Details
Transport Information:
UN 1711 6.1/PG 2

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Reference

Quantification of lidocaine and several metabolites utilizing chemical-ionization mass spectrometry and stable isotope labeling: Quantification of lidocaine and several metabolites utilizing chemical-ionization mass spectrometry and stable isotope labeling. Nelson, S. D.; Garland, W. A.; Breck, G. D.; Trager, W. F. (Dep. Pharm. Chem., Univ. California, San Francisco, Calif., USA). J. Pharm. Sci., 66(8), 1180-90 (English) 1977. CODEN: JPMSAE. DOCUMENT TYPE: Journal CA Section: 1 (Pharmacodynamics) Section cross-reference(s): 25 Quantification of the suspected metabolites of lidocaine-HCl [73-78-9] in humans was carried out using the direct insertion probe and chem.-ionization mass spectrometry. Deuterated analogs of the metabolites of I were added to serial human plasma and urine samples and were used as internal stds. following oral administration of 250 mg of I-HCl to 2 male subjects and 202 mg of I free base to 1 male subject. The av. results after anal. of the 0-24 h urine samples, before .beta.-glucuronidase-sulfatase treatment, indicated the presence of 7 of the possible metabolites in the following amts. (percent of administered dose based on the free base): I 1.95; .omega.-ethylamino- 2,6-dimethylacetanilide [7728-40-7], 4.90; .omega.-amino-2,6-dimethylacetanilide, [18865-38-8] 0.88; m- [34604-55-2] and(or) p-hydroxylidocaine [39942-41-1], 0.73;m [34604-56-3]-and(or) p-hydroxy-.omega.-ethylamino-2,6-dimethylacetanilide [64585-10-0]0.56;2,6-dimethylaniline [87-62-7], 0.97; and 4-hydroxy-2,6-dimethylaniline [3096-70-6], 63.5. There are some commonly used reagents like 64585-21-3 in this article. BothN-ethyl [627-01-0]- and N, N-diethylglycine [1606-01-5] were detected in human and rhesus monkey urine, although quantification was not achieved. .

Preparation of 2,4,5-trimethylaniline and sodium 2,4-dimethylaniline-5-sulfonate, and their effects on liver enzyme activities: Preparation of 2,4,5-trimethylaniline and sodium 2,4-dimethylaniline-5-sulfonate, and their effects on liver enzyme activities. Kamiya, Shozo; Nakamura, Akitada; Takahashi, Atsushi; Anzai, Michiko; Omori, Yoshihito (Natl. Inst. Hyg., Tokyo, Japan). Eisei Shikensho Hokoku, (94), 159-61 (Japanese) 1976. CODEN: ESKHA5. DOCUMENT TYPE: Journal CA Section: 4 (Toxicology) Section cross-reference(s): 7, 17, 25 The metabolites of Ponceau 3R [3564-09-8] and SX [4548-53-2], 2,4,5-trimethylaniline (I) [137-17-7] and Na 2,4-dimethylaniline-5-sulfonate (II) [64501-84-4] were synthesized and these and other related compds. were tested against hepatic enzymes including lactate dehydrogenase [9001-60-9], glucose 6-phosphatase [9001-39-2], glucose 6-phosphate dehydrogenase [9001-40-5], and RNase [9001-99-4] in mice and rats. I and 2,6-dimethylaniline [87-62-7] were less inhibitory than their corresponding 2,4,6- [88-05-1] and 2,4-isomer [95-68-1]. Arom. amines were stronger inhibitors than corresponding sulfonated arom. amines.

Detail of "87-62-7"

Benzenamine,2,6-dimethyl-

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Reference