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Nucleophilic substitutions on carboxylic acid derivatives

Nucleophilic substitutions on carboxylic acid derivatives. X. Kinetics and mechanism of the hydrolysis of N,N-disubstituted thiocarbamic acid chlorides.In this experiment, several chemicals are used like 88-11-9 Bacaloglu, R.; Daescu, C. (Lab. Org. Chem., Polytech. Inst. "Traian Vuia", Timisoara, Rom.Some commonly used reagents like 88-11-9 is used in this experiment.). Rev. Roum. Chim., 22(7), 977-85 (German) 1977. CODEN: RRCHAX. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Rate consts. for the hydrolysis of 8 thiocarbamoyl chlorides RR1NCSCl (R = R1 = Me, Et, Pr, iso-Bu; R = Ph, R1 = Me, Et; RR1N = piperidino, morpholino) were detd. by potentiometric and conductometric measurements. The primary reaction was first order, yielding RR1NH and COS, and the hydrolysis of COS to CO2 and H2S was a 2nd order reaction, the kinetics of which were also detd. ..

Nucleophilic substitutions on carboxylic acid derivatives

Nucleophilic substitutions on carboxylic acid derivatives. X. Kinetics and mechanism of the hydrolysis of N,N-disubstituted thiocarbamic acid chlorides.In this experiment, several chemicals are used like 88-11-9 Bacaloglu, R.; Daescu, C. (Lab. Org. Chem., Polytech. Inst. "Traian Vuia", Timisoara, Rom.Some commonly used reagents like 88-11-9 is used in this experiment.). Rev. Roum. Chim., 22(7), 977-85 (German) 1977. CODEN: RRCHAX. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Rate consts. for the hydrolysis of 8 thiocarbamoyl chlorides RR1NCSCl (R = R1 = Me, Et, Pr, iso-Bu; R = Ph, R1 = Me, Et; RR1N = piperidino, morpholino) were detd. by potentiometric and conductometric measurements. The primary reaction was first order, yielding RR1NH and COS, and the hydrolysis of COS to CO2 and H2S was a 2nd order reaction, the kinetics of which were also detd. ..