Detail of "88762-30-5"

Reference

Thermodynamic study of gaseous ternary oxide molecules

Thermodynamic study of gaseous ternary oxide molecules. The europium-vanadium-oxygen system. Balducci, G.; Gigli, G.; Guido, M. (Ist. Chim. Fis., Univ. Roma, Rome, Italy). J. Chem. Phys., 79(11), 5623-7 (English) 1983. CODEN: JCPSA6. ISSN: 0021-9606. DOCUMENT TYPE: Journal CA Section: 69 (Thermodynamics, Thermochemistry, and Thermal Properties) Section cross-reference(s): 73 The gaseous ternary oxide mols. EuVO3 [39432-21-8] and EuVO2 [88762-30-5] were identified by high temp. mass spectrometry in the vapors in equil. over a mixt. of Eu and V oxides in a Mo cell. From the study of 4 all-gas equil., the dissoc. energies of were derived: (EuVO3) 2192.5 ± 16 (EuVO2) = 1504 ± 11 kJ/mol, resp. The appearance potentials were measured as: 8.1 ± 0.5 and 8 ± 1 eV for EuVO3+ and EuVO2+, resp.