CAS No.89-71-4,Benzoic acid,2-methyl-, methyl ester Suppliers,MSDS download

Detail of "89-71-4"

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CAS Number:

89-71-4

Name:

Benzoic acid,2-methyl-, methyl ester

Superlist Name:

Methyl o-toluate

Molecular Structure:

Formula:

C₉H₁₀O₂

Molecular Weight:

150.18

Synonyms:

o-Toluicacid, methyl ester (6CI,7CI,8CI);2-Methylbenzoic acid methyl ester;2-Toluicacid methyl ester;Methyl 2-methylbenzoate;Methyl 2-toluate;Methylo-methylbenzoate;Methyl orthotoluate;NSC 9402;

EINECS:

201-932-2

Density:

1.045 g/cm³

Boiling Point:

215 °C at 760 mmHg

Flash Point:

82.2 °C

Appearance:

clear colorless liquid

Hazard Symbols:

Risk Codes:

36/37/38

Safety:

37/39-26-36 Details

Reference

Commercial method of producing phthalic anhydride by oxidation of o-xylene in a liquid phase: Commercial method of producing phthalic anhydride by oxidation of o-xylene in a liquid phase. Samter, L. N.; Nikitin, A. K.; Mak, N. E. (USSR). Nov. Metody Sint. Org. Soedin. Osn. Neftekhim. Syr'ya, 39-48. Edited by: Khcheyan, Kh. E. TsNIITEneftekhim: Moscow, USSR. (Russian) 1982. CODEN: 51UAA2. DOCUMENT TYPE: Conference CA Section: 45 (Industrial Organic Chemicals, Leather, Fats, and Waxes) Me o-toluate (I) [89-71-4] under O pressure at 190° gives quant. phthalic anhydride (II) [85-44-9]. This fact is used in a 2-stage oxidn. of o-xylene (III) [95-47-6] to II. The process involves high-pressure oxidn. of 1:3 III-I mixt. at 190°. This reaction gives 1:1 toluic acid (IV) [25567-10-6] - II mixt. After II is sepd., IV is esterified with MeOH to I which is recycled to the III oxidn. stage. A flow diagram of an industrial plant for this process is given.

Conformational analysis of o-substituted methyl benzoates: Conformational analysis of o-substituted methyl benzoates. Gitis, S. S.; Kaminskaya, E. 89-71-4 and 121-98-2 are also occured in this study. G.; Gershkovich, I. M.; Grudtsyn, Yu. D.; Kaminskii, A. Ya. (USSR). Vopr. Stereokhimii. Resp. Mezhved. Nauch. Sb., (5), 89-97 From: Ref. Zh., Khim. 1976, Abstr. No. 20Zh14(Russian) 1976. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) Title only translated. .

Detail of "89-71-4"

Benzoic acid,2-methyl-, methyl ester

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CAS No.89-71-4 Methyl o-toluate

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CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

CAS No.89-71-4 Methyl o-toluate

Reference