Detail of > 89-92-9
- CAS Number:
- 89-92-9
- Name:
Benzene,1-(bromomethyl)-2-methyl-
- Superlist Name:
- 2-Methylbenzyl bromide
- Formula:
- C8H9Br
- Molecular Structure:

- Synonyms:
- o-Xylene, a-bromo- (6CI,7CI,8CI);1-(Bromomethyl)-2-methylbenzene;2-(Bromomethyl)toluene;2-Methylbenzylbromide;2-Xylyl bromide;NSC 60145;o-(Bromomethyl)toluene;o-Methylbenzylbromide;o-Xylyl bromide;a-Bromo-o-xylene;
- Molecular Weight:
- 185.06
- EINECS:
- 201-951-6
- Density:
- 1.368 g/cm3
- Melting Point:
- 16-20 °C(lit.)
- Boiling Point:
- 223.5 °C at 760 mmHg
- Flash Point:
- 82.2 °C
- Solubility:
- practically insoluble in water
- Appearance:
- clear yellow liquid
- Hazard Symbols:
C- Risk Codes:
- 36/37/38-34-20/21/22
- Safety:
- 26-36/37/39-45Details
- Transport Information:
- UN 1701 6.1/PG 2
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Reference
- Dehalogenation of organic halides by flash vacuum pyrolysis over magnesium: a versatile synthetic method
- Dehalogenation of organic halides by flash vacuum pyrolysis over magnesium: a versatile synthetic method. Aitken, R. 89-92-9 which is the cas registry number is also used here. Alan; Hodgson, Philip K. G.; Oyewale, Adebayo O.; Morrison, John J. (Sch. Chem., Univ. St. Andrews, North Haugh/St. Andrews/Fife KY16 9ST, UK). Chemical Communications (Cambridge), (13), 1163-1164 (English) 1997 Royal Society of Chemistry. CODEN: CHCOFS. ISSN: 1359-7345. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) Flash vacuum pyrolysis over magnesium at 600°C results in efficient dehalogenation of a variety of org. halides and provides a preparatively useful method for C-C bond formation and other reactions. .
- C-Cyanation with 1-cyanobenzotriazole
- Katritzky, Alan R.; Akue-Gedu, Rufine; Vakulenko, Anatoliy V.There are some reagents like 89-92-9 is used in this study. (Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA). ARKIVOC (Gainesville, FL, United States), (3), 5-12 (English) 2007 Arkat USA Inc. URL: http://www.arkat-usa.org/ark/journal/2007/I03_Anders/1851/EA-1851D P%20as%20published%20mainmanuscript.pdf. CODEN: AGFUAR. There are some commonly used reagents like 89-92-9 in this article. DOCUMENT TYPE: Journal; (online computer file) CA Section: 21 (General Organic Chemistry) 1-Cyanobenzotriazole is a convenient source of NC+ for C-cyanation with in situ-generated sp3 and sp2 carbanions providing a-cyano sulfones, ketones, alkanecarboxylate esters, cyanides, alkylheterocycles, diarylmethanes and heteroarylcarbonitriles in good to high yields (55-78%). ..
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