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CAS No.: | 9003-27-4 |
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Name: | Polyisobutylene |
Article Data: | 3 |
Molecular Structure: | |
Formula: | (C4H8)n |
Molecular Weight: | 56.10632 |
Synonyms: | Propene, 2-methyl-, polymers;1-Propene,-2-methyl-, homopolymer;2-Methyl-1-propene, homopolymer;Polyisobutene;2-Methylpropene polymer;HSDB 1260;Isobutene homopolymer;Isobutene polymer;Isobutylene homopolymer;Maxvis 2000;UNII-4GAS6381TX; |
EINECS: | 204-066-3 |
Density: | 0.92 g/mL at 25 °C(lit.) |
Melting Point: | 54-56 °C |
Boiling Point: | 300 °C |
Solubility: | Insoluble in water, alcohol and other polar solvents |
Appearance: | Colorless to light yellow viscoelastic material |
Safety: | 24/25 |
PSA: | 0.00000 |
LogP: | 1.70180 |
isobutene
Conditions | Yield |
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With 1,4-bis(o-chloroisopropyl)benzene; triethoxyphenylsilane; titanium tetrachloride In hexane; dichloromethane; isopropyl alcohol at -78 - 20℃; for 2h; | |
With cumenyl chloride; titanium tetrachloride In hexane; dichloromethane at -78 - 50℃; for 0.583333h; Cooling with acetone-dry ice; | |
With pyridine; α,α,α',α'-tetramethyl-1,4-benzene dimethylchloride; titanium tetrachloride In hexane; dichloromethane at -68℃; for 2h; |
isobutene
Conditions | Yield |
---|---|
With 1,4-bis(o-chloroisopropyl)benzene; triethoxyphenylsilane; titanium tetrachloride In hexane; dichloromethane; isopropyl alcohol at -78 - 20℃; for 2h; | |
With cumenyl chloride; titanium tetrachloride In hexane; dichloromethane at -78 - 50℃; for 0.583333h; Cooling with acetone-dry ice; | |
With pyridine; α,α,α',α'-tetramethyl-1,4-benzene dimethylchloride; titanium tetrachloride In hexane; dichloromethane at -68℃; for 2h; |
Conditions | Yield |
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Engelhard F-24 at 135 - 170℃; under 760.051 Torr; for 1.5 - 24h; | |
Engelhard F-24 sulphuric acid activated catalyst at 165 - 200℃; under 2585.81 Torr; for 0.5 - 24h; |
The Polyisobutylene with CAS registry number of 9003-27-4 is also known as Isobutene polymer. The systematic name is 1-Propene, 2-methyl-, homopolymer. It belongs to product categories of Polymers; Butene and Higher Organic Electronics and Photonics; Dielectric Materials; Hydrophobic Polymers; Olefins; Organic Conductors and Photovoltaics;POLB - POLYPolymer Standards. In addition, the formula is (C4H8)n. This chemical is a colorless to light yellow viscoelastic material that insoluble in water, alcohol and other polar solvents.It is a component of new surgical dressing material.When you use it ,avoid contact with skin and eyes. It should be sealed in cool, dry place away from fire, heat. What's more, this chemical is used as dispersant, binder, lubricant additive and also used as raw material for rubber insulation and other products. During using it, avoid contact with skin and eyes.
Preparation of Polyisobutylene:
It is prepared by polymerization of liquid ethylene with methyl chloride or hexane at low temperature. The reaction occurs with catalyst aluminum chloride. After the polymerization, increasing the temperature of the reaction mixture to remove volatile components.