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9003-29-6

Basic Information
CAS No.: 9003-29-6
Name: POLYBUTENES
Article Data: 1076
Molecular Structure:
Molecular Structure of 9003-29-6 (POLYBUTENES)
Formula: C4 H8
Molecular Weight: 58.1234
Synonyms: Butene,polymers (8CI); 100H; 10H; 15R; 1600A; 200SH; 300H; 34R; 40SH; 5H; Amoco 15H; B912; Beaulon P 5040; Butene polymer; C 9900; Chevron 12; Chevron 16; Chevron18; Chevron 6; Cosden OSH; Duraflex 8510; Dynapak H 2000; EIM 8; Glissopal 10;Glissopal 3251; Glissopal 91051; Glissopal 92485; Glissopal 93026; Glissopal93039; Glissopal CE 5203; H 25; HE 175; HE 1975; HE 300; HE 375; HT 300; HV 100;HV 100F; HV 15; HV 15E; HV 300F; HV 300R; HV 35; Hyvis 10; Hyvis 3; Hyvis 5;Hyvis 7000/45; Idemitsu Polybutene 15R; Idemitsu Polybutene 5H; IdemitsuPolybutene OH; Indopol 1900; Indopol 500; Indopol H 15; Indopol H 1800; IndopolH 18000; Indopol H 200; Indopol H 2100; Indopol H 25; Indopol H 40; Indopol H50; Indopol H 7; Indopol L 10; Indopol L 4; L 14; L 14 (polymer); LP 15; LP 15(polyolefin); LV 100; LV 50; LZV 100; NA; NA (solvent); NA Solvent NAS 5H; NAS5H; Napvis 2000; Napvis 3; Napvis 600; Napvis D 30; Napvis DE 10; NeosealerMS-N 12; Nissan Polybutene 015N; Nissan Polybutene 06N; Nissan Polybutene 06SH;Nissan Polybutene 200N; Nissan Polybutene 200SH; Nissan Polybutene 5N; NissekiHV 100; Nisseki HV 1000; Nisseki HV 15; Nisseki HV 300F; Nisseki HV 35; NissekiLV 10; Nisseki LV 100; Nisseki LV 15; Nisseki LV 5; Nisseki LV 50; NissekiPolybutene HV 300F; Nisseki Polybutene LV 50; Oktol 600; Oloa 9350; Oronite 6;PB 0800; PB 100R; PB 1300; PB 1500; PB 15H; PB 2110; PB 4137; PB 8510; PH 162;PM 2060; PO 300H; Parapol 450; Parapol 700; Petrofin 100; Poly SH 1900; Poly SH2500; Poly-n-butene; Polybuden 300H; Polybutene; Polybutene 06N; Polybutene 0H;Polybutene 100H; Polybutene 15R; Polybutene 2000; Polybutene 300H; PolybuteneHT-A; Polybutene HV 100; Polybutene HV 35; Polybutene LV 50; Polybutene ON;Polybutene PB 5H; Polybutene SH 015; Polybutylene; Polyvis; Polyvis 015N;Polyvis 025SH; Polyvis 06N; Polyvis 06SH; Polyvis 0N; Polyvis 10N; Polyvis150SH; Polyvis 2000CH; Polyvis 200N; Polyvis 200SH; Polyvis 300H; Polyvis 3SH;Polyvis 5N; Polyvis NC 7000; Polyvis ON; Polyvis OO; RHV 300; ResinKit 22;
Density: g/cm3
Melting Point: 94.3-104.8 °C
Boiling Point: 112.2°Cat760mmHg
Flash Point: 12.6°C
Safety: Low toxicity by inhalation. When heated to decomposition it emits acrid smoke and irritating vapors.
PSA: 0.00000
LogP: 3.16480
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Chemistry

The liquid is clear and colourless, and is sold in many different grades. The grades are determined mainly by molecular weight, the higher grades showing increasing viscosity. The oligomer degrades at high temperature (upwards of 350 C) to form monomer isobutene by chains unzipping from the chain ends.
Empirical Formula: C8H16 
Molecular Weight: 112.2126 
Flash Point: 12.6 °C 
Boiling Point: 112.2 °C at 760 mmHg
Synonyms:BUTENE POLYMER;POLYBUTENES; POLYBUTENE;15h;2000h; 300h; amoco15h;amocoh300
Molecular Structure:

Uses

POLYBUTENES(9003-29-6) is used as an additive for engine oils and greases, and as an extender in putty used for sealing roofs and windows. In hydrogenated form, POLYBUTENES(9003-29-6) is also used in a wide variety of cosmetic preparations, such as lipstick. It is used in adhesives owing to its tackiness.

Toxicity Data With Reference

   

Ihl-rat TCLo:700 mg/m3/7H/2W-I

   ENVRAL    Environmental Research. 53 (1990),48.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Low toxicity by inhalation. When heated to decomposition it emits acrid smoke and irritating vapors.

Specification

Oxidation
But the same double bond makes the molecule sensitive to oxidation when hot liquid is exposed to air. The polymer degradation reaction produces aldehydes and ketones, which are the further oxidised to carboxylic acids. This causes loss of tack and makes the material soluble in water.