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Detail of "91-00-9"

  • MSDS Download
  • CAS Number:
  • 91-00-9
  • Name:

  • Benzenemethanamine,a-phenyl-

  • Superlist Name:
  • Aminodiphenylmethane
  • Molecular Structure:
  • Formula:
  • C13H13N
  • Molecular Weight:
  • 183.25
  • Synonyms:
  • Benzhydrylamine;(Diphenylmethyl)amine;1,1-Diphenylmethylamine;Methanamine, 1,1-diphenyl-;alpha-Phenylbenzenemethanamine;alpha-Phenylbenzylamine;UNII-4BO6ISS9DX;NSC 49127;Methylamine, 1,1-diphenyl- (6CI,7CI,8CI);
  • EINECS:
  • 202-032-2
  • Density:
  • 1.057 g/cm3
  • Melting Point:
  • 12 °C
  • Boiling Point:
  • 301.1 °C at 760 mmHg
  • Flash Point:
  • 141.8 °C
  • Solubility:
  • slightly soluble in water
  • Appearance:
  • colorless liquid
  • Hazard Symbols:
  • HarmfulXn,IrritantXi
  • Risk Codes:
  • 22-36/37/38
  • Safety:
  • 26-36 Details
  • Transport Information:
  • UN 2735 8/PG 3
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Aminodiphenylmethane,Cas#91-00-9

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AMINODIPHENYLMETHANE (BENZHYDRYLAMINE) (P)

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Reference

Analogs of sparteine
Analogs of sparteine. 5. Antiarrhythmic activity of selected N,N'-disubstituted bispidines. Ruenitz, Peter C.; Mokler, Corwin M. (Sch. Pharm., Univ. Georgia, Athens, Ga., USA). J. Med. Chem., 20(12), 1668-71 (English) 1977. CODEN: JMCMAR. DOCUMENT TYPE: Journal CA Section: 1 (Pharmacodynamics) Section cross-reference(s): 28 Seven title compds., inner ring analogs of sparteine, were tested for antiarrhythmic potency by the mouse-chloroform fibrillation assay and for acute toxicity in mice. Several compds. had antiarrhythmic potency comparable to sparteine, but were somewhat less toxic. N-benzhydryl-N'-methylbispidine-HCl (I) [64304-24-1] was prepd. by the cyclization reaction of N-methyl-4-piperidone [1445-73-4] with benzhydrylamine [91-00-9] and paraformaldehyde followed by reaction with alk. NH2NH2. Activity-lipophilicity (partition coeff.) relations are discussed.Several substances are used for example 64304-25-2 which is its cas registry number. Sparteine and 2 title analogs showed no signs of binding of Ca2+ or Mg2+ as detd. by NMR anal. .
Enantioselective synthesis of b-amino esters through high pressure-induced addition of amines to a,b-ethylenic esters
Enantioselective synthesis of b-amino esters through high pressure-induced addition of amines to a,b-ethylenic esters. D'Angelo, Jean; Maddaluno, Jacques (Unite Chim. Org., ESPCI, Paris 75231/05, Fr.). J. Am. Chem. Soc., 108(25), 8112-14 (English) 1986. CODEN: JACSAT. ISSN: 0002-7863. 91-00-9 which is the cas registry number of some chemical is mentioned. DOCUMENT TYPE: Journal CA Section: 34 (Amino Acids, Peptides, and Proteins) The enantioselective synthesis of 10 b-amino acid esters I [R = (R,S)-, (R)-, or (S)-PhMeCH, Ph2CH2, (R,S)-1-mesitylethyl; R1 = Me, (MeO)2CHCH2; R2 = Me, l-menthyl, 8-phenylmenthyl, 8-(p-tert-butylphenyl)menthyl, 8-(p-phenoxyphenyl)menthyl, 8-(b-naphthyl)menthyl] was achieved by the Michael addn. of amines RNH2 to a,b-ethylenic esters II under high pressure (5-15 kbar). High stereocontrol at the newly created asym. center in I was achieved when R2 was an 8-phenylmenthyl deriv. Thus, <99% diastereoisomeric excess was obtained when R2 = 8-(b-naphthyl)menthyl. .
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