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| CAS No.: | 91-23-6 |
|---|---|
| Name: | 2-Nitroanisole |
| Article Data: | 170 |
| Molecular Structure: | |
|
|
|
| Formula: | C7H7NO3 |
| Molecular Weight: | 153.137 |
| Synonyms: | Ortho-Nitro anisole;o-nitroanisole;O-Nitro anisole;O-Nitroanisole; l-Methoxy-2nitrobenzene;o-Nitrophenyl methyl ether;2-Methoxy-1-nitrobenzene;1-Nitro-2-methoxybenzene;Benzene, 1-methoxy-2-nitro-;Anisole, o-nitro-;ortho-Nitrobenzene methyl ether;2-Methoxynitrobenzene;1-methoxy-2-nitro-benzene; |
| EINECS: | 202-052-1 |
| Density: | 1.222 g/cm3 |
| Melting Point: | 9-12 °C(lit.) |
| Boiling Point: | 277 °C at 760 mmHg |
| Flash Point: | 127 °C |
| Solubility: | 1.45 g/L (20 ºC) |
| Appearance: | yellow to amber liquid |
| Hazard Symbols: |
 T
|
| Risk Codes: | 45-22 |
| Safety: | 53-45 |
| Transport Information: | UN 2730 6.1/PG 3 |
| PSA: | 55.05000 |
| LogP: | 2.12660 |
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- Total:22 Page 1 of 1 1
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Chemistry
IUPAC Name:1-methoxy-2-nitrobenzene
Molecular Formula:C7H7NO3
Molecular Weight:153.135380 g/mol
Appearance:colorless to yellowish liquid
Melting Point:9-12 °C(lit.)
Boiling Point:273 °C(lit.)
Flash Point:>230 °F
Solubility:ethanol and ether
Density:1.254 g/mL at 25 °C(lit.)
Refractive index:n20/D 1.561(lit.)
Water Solubility:1.45 g/L (20 °C)
Merck:14,6585
BRN:1868032
EINECS:202-052-1
Synonyms of O-NITROANISOLE(91-23-6):
1-methoxy-2-nitro-benzen;1-Nitro-2-methoxybenzene;2-Methoxy-1-nitrobenzene;Anisole, o-nitro-;Benzene,1-methoxy-2-nitro-;NCI-C60388;o-Nitro(methoxy)benzene;o-nitro-anisol;2-Nitroanisole
Categories of O-NITROANISOLE(91-23-6):
Intermediates of Dyes and Pigments
Uses
Production
Toxicity Data With Reference
| 1. | mmo-sat 666 µg/plate | ENMUDM Environmental Mutagenesis. 5 (Suppl 1)(1983),3. | ||
| 2. | mma-sat 20 µmol/plate | MUREAV Mutation Research. 58 (1978),11. | ||
| 3. | orl-rat LD50:1980 mg/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (8)(1981),50. | ||
| 4. | orl-rat LD50:740 mg/kg | GISAAA Gigiena i Sanitariya 51 (1)(1986),85. | ||
| 5. | orl-mus LD50:1300 mg/kg | GISAAA Gigiena i Sanitariya 51 (1)(1986),85. |
Consensus Reports
Safety Profile
Hazard Codes:T
Risk Statements:45-22
45:May cause cancer
22:Harmful if swallowed
Safety Statements:53-45
53:Avoid exposure - obtain special instruction before use
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR:UN 2730 6.1/PG 3
WGK Germany:3
RTECS:BZ8790000
HazardClass:6.1
PackingGroup:III
HS Code:29093090
Confirmed carcinogen. Moderately toxic by ingestion. Mutation data reported. Explosive reaction with sodium hydroxide + zinc. Vigorous reaction with hydrogen + catalyst (at 250°C/34bar). When heated to decomposition it emits toxic fumes of NOx. See also p-NITROANISOLE.
Standards and Recommendations
Specification
First Aid Measures of O-NITROANISOLE(91-23-6):
Ingestion:If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin:Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Storage of O-NITROANISOLE(91-23-6):
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.