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92-53-5

Basic Information
CAS No.: 92-53-5
Name: 4-Phenylmorpholine
Article Data: 400
Molecular Structure:
Molecular Structure of 92-53-5 (4-Phenylmorpholine)
Formula: C10H13NO
Molecular Weight: 163.219
Synonyms: (4-Morpholinyl)benzene;Morpholinobenzene;N-Phenylmorpholine;NSC 239125;NSC 2628;
EINECS: 202-164-0
Density: 1.068 g/cm3
Melting Point: 51-54 °C(lit.)
Boiling Point: 264.8 °C at 760 mmHg
Flash Point: 80.6 °C
Solubility: water: 3.46 g/L
Appearance: white to brownish crystalline solid
Hazard Symbols: ToxicT
Risk Codes: 22-24
Safety: 36/37-45-36/37/39-28A
Transport Information: UN 2811 6.1/PG 3
PSA: 12.47000
LogP: 1.58820
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Chemistry

The Molecular formula of PHENYL MORPHOLINE(92-53-5):C10H13NO   
The Molecular Weight of PHENYL MORPHOLINE(92-53-5):163.22
The Molecular Structure of PHENYL MORPHOLINE(92-53-5) is:
Density:1.068 g/cm3 
Melting point:51-54 °C(lit.)
Boiling point:264.8 °C at 760 mmHg 
Flash point:80.6 °C   
Solubility in water:3.46 g/L
Index of Refraction:1.541   
Molar Refractivity:48.06 cm3
Molar Volume:152.7 cm3
Polarizability:19.05 10-24cm
Surface Tension:38.7 dyne/cm
Enthalpy of Vaporization:50.27 kJ/mol  
Vapour Pressure:0.00952 mmHg at 25°C
Appearance:white to brownish crystalline solid  
IUPAC Name:4-phenylmorpholine
Synonyms:MORPHOLINOBENZENE;PHENYLMORPHOLINE,N-;4-PHENYLMORPHOLINE;N-PHENYLMORPHOLINE;(4-Morpholinyl)benzene;4-phenyl-morpholin;Morpholine,4-phenyl-;Morpholinobenzol 

Toxicity Data With Reference

1.   

eye-rbt 5 mg MLD

   UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/13 ,1972.
2.   

orl-rat LD50:930 mg/kg

   JIHTAB    Journal of Industrial Hygiene and Toxicology. 23 (1941),259.
3.   

skn-rbt LD50:360 mg/kg

   UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/13 ,1972.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by skin contact. Moderately toxic by ingestion. An eye irritant. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes:T
T:Toxic
Risk Statements
R22:Harmful if swallowed.   
R24:Toxic in contact with skin.
Safety Statements
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
RIDADR:UN 2811 6.1/PG 3
WGK Germany:2
RTECS:QE8575000
HazardClass:6.1(b)
PackingGroupIII
HS Code:29349990

 

Specification

Chemical Stability: Not available 
Incompatibilities with Other Materials Strong oxidizing agents, strong acids.
Conditions to Avoid: Incompatible materials.   
Hazardous Decomposition Products Nitrogen oxides, carbon monoxide, carbon dioxide. 
Hazardous Polymerization Has not been reported.