Reference

Initiation reaction of monomer radicals in an aqueous potassium persulfate solution saturated with styrene

Initiation reaction of monomer radicals in an aqueous potassium persulfate solution saturated with styrene. Oganesyan, A. A.; Airapetyan, K. S.; Gukasyan, A. V.; Kinoyan, F. S. (Inst. Org. Khim., Yerevan, USSR). Dokl. - Akad. Nauk Arm. SSR, 82(3), 134-6 (Russian) 1986. CODEN: DANAAW. ISSN: 0366-8606. DOCUMENT TYPE: Journal CA Section: 35 (Chemistry of Synthetic High Polymers) Interfacial polymn. of styrene [100-42-5] in a K2S2O8 catalyst aq. soln.-styrene binary system was accompanied by the reactions in aq. phase between sulfate ion radicals and styrene and between these radicals and H2O. The 2nd reaction resulted in HO× radicals which reacted with styrene to form MOCH2PhHC× radicals. These radicals reacted with HO× radicals to form HOCH2CHOHPh [93-56-1] which oxidized to benzaldehyde [100-52-7]. The formation of the above compds. was confirmed by pH measurements, IR spectra, and chromatog. At K2S2O8 concn. >1.In this experiment, several chemicals are used like 100-52-7 and 7727-21-1 5%, the above reactions prevailed completely, and the polymn. (in aq. phase) was almost totally suppressed. .

The metabolism of styrene oxide in the isolated perfused rat liver

The metabolism of styrene oxide in the isolated perfused rat liver. Identification and quantitation of major metabolites. Ryan, Adrian J.; Bend, John R. (Pharmacol. Branch, Natl. Inst. Environ. Health Sci., Research Triangle Park, N. C., USA). Drug Metab. Dispos., 5(4), 363-7 (English) 1977. CODEN: DMDSAI. DOCUMENT TYPE: Journal CA Section: 4 (Toxicology) Isolated perfused rat livers rapidly metabolized 14C-labeled styrene oxide (I) [96-09-3]. A large proportion of the administered radioactivity was excreted in the bile as a single compd. that was identified as S-(1-phenyl-2-hydroxyethyl)glutathione [64186-97-6] by comparison with an authenitc synthetic std. The circulating perfusate was found to contain approx. equal amts. of styrene glycol [93-56-1], mandelic acid [90-64-2], and the glutathione deriv.