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Detail of "930-96-1"

  • MSDS Download
  • CAS Number:
  • 930-96-1
  • Name:

  • 2-Thiophenecarboxaldehyde,3-bromo-

  • Superlist Name:
  • 3-Bromothiophene-2-carbaldehyde
  • Molecular Structure:
  • Formula:
  • C5H3BrOS
  • Molecular Weight:
  • 191.05
  • Synonyms:
  • 3-Bromo-2-formylthiophene;3-Bromo-2-thiophenecarboxaldehyde;3-Bromothiophene-2-aldehyde;
  • Density:
  • 1.789 g/cm3
  • Melting Point:
  • 25 °C
  • Boiling Point:
  • 250.3 °C at 760 mmHg
  • Flash Point:
  • 105.2 °C
  • Hazard Symbols:
  • IrritantXi,HarmfulXn
  • Risk Codes:
  • 36/37/38-20/21/22
  • Safety:
  • 26-36/37/39-22 Details
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CAS No.930-96-1 3-Bromothiophene-2-carbaldehydeCompetitive Product

Assay:≥97%  Appearance:solid  Package:g~kg

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Reference

Ring cleavage of a 3-azidothiophene: novel extrusion of acetylene
Ring cleavage of a 3-azidothiophene: novel extrusion of acetylene. Moody, Christopher J.; Rees, Charles W.; Tsoi, Siu Chung (Dep. 930-96-1 are also occured in this study. Chem., Imp. Coll. Sci. Technol., London SW7 2AY, UK). J. Chem. Soc., Perkin Trans. 1, (5), 915-20 (English) 1984. CODEN: JCPRB4. ISSN: 0300-922X. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Section cross-reference(s): 28 Thermolysis of azidothiophene I in refluxing PhMe for 0.5 h resulted in ring cleavage with extrusion of HCYCH giving 19% isotriazole II together with 17% pyridazinecarboxylate III: in refluxing xylene the yields of II and III were 27 and 26%, resp. The ring cleavage represents the 1st fragmentation of a 5-membered heteroarom. b-nitrene to extrude an alkyne. The reaction proceeds through coordination of the derived nitrene with the S to facilitate ring cleavage. .
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