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Detail of "932-41-2"

  • CAS Number:
  • 932-41-2
  • Name:
  • 2,3-Thiophenedicarboxaldehyde

  • Molecular Structure:
  • Formula:
  • C6H4O2S
  • Molecular Weight:
  • 140.16
  • Synonyms:
  • 2,3-Bisthiophenecarboxaldehyde;2,3-Diformylthiophene;
  • Density:
  • 1.37 g/cm3
  • Melting Point:
  • 76-78 °C(lit.)
  • Boiling Point:
  • 308.4 °C at 760 mmHg
  • Flash Point:
  • 140.3 °C

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CAS No.932-41-2 2,3-ThiophenedicarboxaldehydeCompetitive Product

2,3-Thiophenedicarboxaldehyde

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CAS No.932-41-2 2,3-Thiophenedicarboxaldehyde

2,3-Dicarbaldehyde thiophene

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CAS No.932-41-2 2,3-Thiophenedicarboxaldehyde

2,3-Thiophenedicarboxaldehyde

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Reference

Synthesis of triphenyleno[2,3-b]thiophene derivatives
Synthesis of triphenyleno[2,3-b]thiophene derivatives. Nicolaides, D. N. (Lab. Org. Chem., Univ. Thessaloniki, Salonika, Greece). Synthesis, (10), 675-7 (English) 1976. CODEN: SYNTBF.Several substances with their cas registry numbers 61458-10-4 and 932-41-2 may be metioned in this study. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) 9,13-Dihydrotriphenyleno[2,3-b]thiophene (I; X = H2) was prepd. in 18% yield by Wittig reaction of 2,3-thiophenedicarboxaldehyde with (o-Ph3P+CH2C6H4)2.cntdot.2Br-. I (X = O) was obtained in 75% yield by oxidn. Dehydrogenation of I (X = H2) gave 88% II (n = 0), which was oxidized to give 63% II (n = 2). .
Bis-Wittig reactions of thiophene-2,3-dicarbaldehyde with 1,2- and 1,4-bis-ylids
Bis-Wittig reactions of thiophene-2,3-dicarbaldehyde with 1,2- and 1,4-bis-ylids. Nicolaides, D. N. (Lab. Org. Chem., Univ. Thessaloniki, Salonika, Greece).Several substances with their cas registry numbers 62486-08-2 and 932-41-2 may be metioned in this study. Synthesis, (2), 127-9 (English) 1977. CODEN: SYNTBF. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Reaction of the title aldehyde with ylid I, Ph3P:CHCH2CH2CH:PPh3, and o-[Ph3P:CH]2C6H4 gave II, III, and IV in 0.9, 11, and 20% yield, resp. Treatment of IV with K gave either the 10,11- or 4,5-dihydro deriv. .
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