Detail of "936-72-1"
- CAS Number:
- 936-72-1
- Name:
Benzene,1-methyl-2-(2-propen-1-yloxy)-
- Molecular Structure:
- Formula:
- C10H12O
- Molecular Weight:
- 148.2
- Synonyms:
- Benzene,1-methyl-2-(2-propenyloxy)- (9CI);Ether, allyl o-tolyl (6CI,7CI,8CI);1-Methyl-2-[(2-propenyl)oxy]benzene;2-Allyloxytoluene;Allyl 2-methylphenylether;Allyl o-methylphenyl ether;Allyl o-tolyl ether;NSC 103149;
- Density:
- 0.939 g/cm3
- Boiling Point:
- 206.5 °C at 760 mmHg
- Flash Point:
- 76.5 °C
- Risk Codes:
- 36/37/38
- Safety:
- 26-36/37/39 Details
Benzene,1-methyl-2-(2-propen-1-yloxy)-
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Reference
- Studies on the Claisen rearrangement
- Studies on the Claisen rearrangement. I. The effect of the substituents on the Claisen rearrangement of allyl [o(or p)-substituted phenyl] ethers. Hayashi, Takatoshi; Goto, Masanobu (Fac. Sci. Eng., Ritsumeikan Univ.There are some reagents like 936-72-1 is used in this study., Kyoto, Japan). Nippon Kagaku Kaishi, (10), 1512-17 (Japanese) 1977. CODEN: NKAKB8. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) The effect of ortho and para substituents on the Claisen rearrangement of allyl substituted Ph ethers and the effect of ortho substituents on the conversion was examd. The order of the magnitude of the conversion for para-substituents was: MeO>Me~Me3C>Cl>H>CHO>Ac>NO2. The conversion decreased with increasing electronegativity of the substitutent. For the ortho substituted compds. the substituent effect was: NO2>Cl>Ac>Me>Me3C~CHO>H. There are some commonly used reagents like 936-72-1 in this article. The magnitude of the conversion of ortho substituted compds. reflected the intramol. mutual repulsion of the dipole between the ether O atom and the substituent. The UV, NMR and dipole moments of the allyl Ph ethers were discussed. ..
- Studies on the Claisen rearrangement
- Studies on the Claisen rearrangement. I. The effect of the substituents on the Claisen rearrangement of allyl [o(or p)-substituted phenyl] ethers. Hayashi, Takatoshi; Goto, Masanobu (Fac. Sci. Eng., Ritsumeikan Univ.There are some reagents like 936-72-1 is used in this study., Kyoto, Japan). Nippon Kagaku Kaishi, (10), 1512-17 (Japanese) 1977. CODEN: NKAKB8. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) The effect of ortho and para substituents on the Claisen rearrangement of allyl substituted Ph ethers and the effect of ortho substituents on the conversion was examd. The order of the magnitude of the conversion for para-substituents was: MeO>Me~Me3C>Cl>H>CHO>Ac>NO2. The conversion decreased with increasing electronegativity of the substitutent. For the ortho substituted compds. the substituent effect was: NO2>Cl>Ac>Me>Me3C~CHO>H. There are some commonly used reagents like 936-72-1 in this article. The magnitude of the conversion of ortho substituted compds. reflected the intramol. mutual repulsion of the dipole between the ether O atom and the substituent. The UV, NMR and dipole moments of the allyl Ph ethers were discussed. ..