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94-70-2

Basic Information
CAS No.: 94-70-2
Name: o-Phenetidine
Article Data: 45
Molecular Structure:
Molecular Structure of 94-70-2 (o-Phenetidine)
Formula: C8H11NO
Molecular Weight: 137.181
Synonyms: o-Phenetidine(7CI,8CI);2-Aminophenetole;2-Ethoxyaniline;2-Ethoxybenzenamine;2-Ethoxyphenylamine;NSC 9818;o-Ethoxyaniline;
EINECS: 202-356-4
Density: 1.051 g/cm3
Melting Point: -20 °C
Boiling Point: 231.9 °C at 760 mmHg
Flash Point: 99.2 °C
Solubility: water: 0.5-1.0 g/100 mL at 24.5 °C
Appearance: deep red liquid
Hazard Symbols: ToxicT,IrritantXi
Risk Codes: 23/24/25-33
Safety: 28-36/37-45-28A
Transport Information: UN 2311 6.1/PG 3
PSA: 35.25000
LogP: 2.24870
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    Tel:15900395419

    Address:No.2, Hua tian Rd, Huayuan Industrial Park ,Bin hai Hi-Tech District

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  • 2-ethoxyaniline

  • Casno:

    94-70-2

    2-ethoxyaniline

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    ≥99%, stockAppearance:deep red liquid Package:1kg/bottle;50kg/100kg/drum Application:OLED Transportation:by air, by sea

    We are specialized in manufacturing Organic Optoelectronic Chemicals, especially for OLED (Organic Light Emitting Diode) and OPC (Organic Photo Conductor) materials, Pharmaceutical

  • Springchem New Material Technology Co.,Limited

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    Tel:86-21-62885108

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  • o-Phenetidine

  • Casno:

    94-70-2

    o-Phenetidine

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    Good Price, prompt shipment Application:Medical intermediate; Used in organic synthesis

    Skyrun Industrial Co.Limited (CSR Ind), established in 2003, a state-controlled company(By Skyrun Corp. & High Hope) in China, specializing in developing, producing and handing ra

  • Skyrun Industrial Co.,Ltd

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  • 2-Ethoxyaniline

  • Casno:

    94-70-2

    2-Ethoxyaniline

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    High purity,Competitive Price,Leading Company in the filed. Application:Pharmaceutical Intermediate

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  • o-Phenetidine

  • Casno:

    94-70-2

    o-Phenetidine

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    FOB Price:  USD $ 0.0-0.0

    o-PhenetidineAppearance:Colorless transparent liquid Storage:Keep away of light, cool place Package:as customer’s request Application:pharmaceutical intermediates Transportation:by Sea,air or Express

    yierdechem is a young and potential team, with about ten years experiences in the field of pharmaceutical intermediate and fine chemicals, yierdechem has established solid business

  • Hangzhou Yierdechem Co. Ltd

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    Tel:+86-571-86904883

    Address:903,zhijiang Minglou, Xiasha EDA, Hangzhou City 310018,P.R.China

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Consensus Reports

Reported in EPA TSCA Inventory.

Specification

The IUPAC name of o-Phenetidine is 2-ethoxyaniline. With the CAS registry number 94-70-2, it is also named as 1-Amino-2-ethoxybenzene; 2-Ethoxybenzenamine. It is deep red liquid which is slightly soluble in water. Furthermore, this chemical is very sensitive to exposure to light and air. It neutralizes acids in exothermic reactions to form salts plus water. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. 

The other characteristics of this product can be summarized as: (1)ACD/LogP: 1.62; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.58; (4)ACD/LogD (pH 7.4): 1.62; (5)ACD/BCF (pH 5.5): 9.22; (6)ACD/KOC (pH 5.5): 166.28; (7)ACD/KOC (pH 7.4): 181.89; (8)#H bond acceptors: 2; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 3; (11)Index of Refraction: 1.544; (12)Molar Refractivity: 41.8 cm3; (13)Molar Volume: 132.2 cm3; (14)Polarizability: 16.57×10-24 cm3; (15)Surface Tension: 38.5 dyne/cm; (16)Enthalpy of Vaporization: 46.86 kJ/mol; (17)Vapour Pressure: 0.0608 mmHg at 25°C; (18)Rotatable Bond Count: 2; (19)Exact Mass: 137.084064; (20)MonoIsotopic Mass: 137.084064; (21)Topological Polar Surface Area: 35.2; (22)Heavy Atom Count: 10.

Preparation of o-Phenetidine: It can be obtained by 2-nitro-phenetole with reagent H2 and catalytic agent Pd.

Uses of o-Phenetidine: It is used as a dye, perfume, pharmaceutical intermediates. It is also used in organic synthesis. For example: It can react with nicotinonitrile to get N-(2-ethoxy-phenyl)-nicotinamidine. This reaction needs reagent Fe(NO3)3*9H2O, liq. NH3/powd. sodium and solvent diethyl ether. The reaction time is 3 hours. The yield is 70%.

When you are using this chemical, please be cautious about it as the following:
It is toxic by inhalation, in contact with skin and if swallowed. After contact with skin, wash immediately with plenty of soap-suds. If you want to contact this product, you must wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure.
1. Smiles: c1(c(cccc1)N)OCC;
2. InChI: InChI=1/C8H11NO/c1-2-10-8-6-4-3-5-7(8)9/h3-6H,2,9H2,1H3.

The following are the toxicity data which has been tested.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LDLo oral 600mg/kg (600mg/kg)   Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 52, Pg. 215, 1956.
rabbit LD50 oral 600mg/kg (600mg/kg)   Nippon Yakurigaku Zasshi. Japanese Journal of Pharmacology. Vol. 52, Pg. 215, 1956.