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95-68-1

Basic Information
CAS No.: 95-68-1
Name: 2,4-Dimethyl aniline
Article Data: 116
Molecular Structure:
Molecular Structure of 95-68-1 (2,4-Dimethyl aniline)
Formula: C8H11N
Molecular Weight: 121.182
Synonyms: 2,4-Xylidine(8CI);1-Amino-2,4-dimethylbenzene;2,4-Xylidine;2,4-Dimethylbenzenamine;2,4-Dimethylphenylamine;2,4-Xylylamine;4-Amino-1,3-dimethylbenzene;4-Amino-1,3-xylene;Benzenamine,2,4-dimethyl-;m-Xylidine;
EINECS: 202-440-0
Density: 0.975 g/cm3
Melting Point: 16 °C
Boiling Point: 214.7 °C at 760 mmHg
Flash Point: 90.6 °C
Solubility: 5 g/L (20 °C) in water
Appearance: Colourless to yellow or dark brown liquid
Hazard Symbols: ToxicT, DangerousN
Risk Codes: 23/24/25-33-51/53
Safety: 28-36/37-45-61-28A
Transport Information: UN 1711 6.1/PG 2
PSA: 26.02000
LogP: 2.46680
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Chemistry


IUPAC Name: 2,4-Dimethylaniline
Molecular Formula: C8H11N
Molecular Weight: 121.18 g/mol
Canonical SMILES: c1(c(ccc(c1)C)N)C
InChI: InChI=1/C8H11N/c1-6-3-4-8(9)7(2)5-6/h3-5H,9H2,1-2H3
EINECS: 202-440-0
Classification Code: Mutation data; Tumor data
Product Categories: Intermediates of Dyes and Pigments; Intermediates; Amines
XLogP3: 1.7
H-Bond Donor: 1
H-Bond Acceptor: 1
Surface Tension: 37.9 dyne/cm
Density: 0.975 g/cm3
Flash Point: 90.6 °C
Enthalpy of Vaporization: 45.1 kJ/mol
Boiling Point: 214.7 °C at 760 mmHg
Water Solubility: 5 g/L (20 °C)
Melting Point: 16 °C
Vapor Density: 4.2 (vs air)
Vapour Pressure of 2,4-Xylidine (CAS NO.95-68-1): 0.154 mmHg at 25 °C

Uses

 2,4-Xylidine (CAS NO.95-68-1) is commonly used as intermediates for pesticides, medicine and dyes.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 149ppm/7H (149ppm)   "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986Vol. 6, Pg. 1743, 1991.
mouse LD50 oral 250mg/kg (250mg/kg)   National Technical Information Service. Vol. PB214-270,
rat LD50 oral 467mg/kg (467mg/kg)   National Technical Information Service. Vol. PB214-270,

Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 16 ,1978,p. 367.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory.

Safety Profile

Suspected carcinogen. Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes: ToxicT, Dangerous
Risk Statements: 23/24/25-33-51/53
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed. 
R33: Danger of cumulative effects. 
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 28-36/37-45-61
S28: After contact with skin, wash immediately with plenty of soap-suds. 
S36/37: Wear suitable protective clothing and gloves. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 1711 6.1/PG 2
WGK Germany: 2
RTECS: ZE8925000
HazardClass: 6.1
PackingGroup 2,4-Xylidine (CAS NO.95-68-1): II

Standards and Recommendations

DFG MAK: Animal Carcinogen, Suspected Human Carcinogen

Analytical Methods

For occupational chemical analysis use NIOSH: Amines, Aromatic, 2002.

Specification

 2,4-Xylidine (CAS NO.95-68-1), its Synonyms are 1-Amino-2,4-dimethylbenzene ; 2,4-Dimethylaniline ; 2,4-Dimethylbenzenamine ; 2,4-Dimethylphenylamine ; 2-Methyl-p-toluidine ; 4-Amino-1,3-dimethylbenzene ; Aniline, 2,4-dimethyl- ; Benzenamine, 2,4-dimethyl- ; m-Xylidine ; meta-Xylidine ; 4-Methyl-o-toluidine . It is colourless to yellow or dark brown liquid. It may be sensitive to prolonged exposure to air, slightly soluble in water.