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| CAS No.: | 96-18-4 |
|---|---|
| Name: | 1,2,3-TRICHLOROPROPANE |
| Article Data: | 84 |
| Molecular Structure: | |
|
|
|
| Formula: | C3H5Cl3 |
| Molecular Weight: | 147.432 |
| Synonyms: | Allyl trichloride;Glycerol trichlorohydrin;NSC35403;Trichlorohydrin; |
| EINECS: | 202-486-1 |
| Density: | 1.309 g/cm3 |
| Melting Point: | -14 °C |
| Boiling Point: | 156.8 °C at 760 mmHg |
| Flash Point: | 82.2 °C |
| Solubility: | water: 2 g/L (25 °C) |
| Appearance: | Clear colorless to pale yellow liquid |
| Hazard Symbols: |
 T, F
|
| Risk Codes: | 45-60-20/21/22-39/23/24/25-23/24/25-11-38 |
| Safety: | 53-45-36/37-37-36 |
| Transport Information: | UN 2810 6.1/PG 3 |
| PSA: | 0.00000 |
| LogP: | 2.07140 |
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Chemistry
IUPAC Name: 1,2,3-Trichloropropane
The MF of 1,2,3-Trichloropropane (96-18-4) is C3H5Cl3.
The MW of 1,2,3-Trichloropropane (96-18-4) is 147.43.
Synonyms of 1,2,3-Trichloropropane (96-18-4): 1,2,3-Trichloro-propan ; 1,2,3-Trichlorpropan ; Allyl trichloride ; Allyltrichloride ; Glycerintrichlorhydrin ; Glyceryl trichlorohydrin ; Glyceryltrichlorohydrin
Product Categories: Organics;Analytical Chemistry;Standard Solution of Volatile Organic Compounds for Water & Soil Analysis;Standard Solutions (VOC);Method 552Volatiles/ Semivolatiles;500 Series Drinking Water Methods;ChloroEPA;EPA
Form: Clear colorless to pale yellow liquid
Water Solubility: 2 g/L (25 ºC)
Index of Refraction: 1.453
EINECS: 202-486-1
Density: 1.309 g/ml
Flash Point: 82.2 °C
Boiling Point: 156.8 °C
Melting Point: -14 °C
Storage temp: -20 °C
BRN: 1732068
Uses
1,2,3-Trichloropropane (96-18-4) is used to produce 1,2,3-allyl chloride and also a good solvent. Also for pesticides chlormequat and oats enemy raw materials.
Production
1,2,3-Trichloropropane is sensitive to prolonged exposure to light. Sensitive to heat. May react with active metals, strong caustics and oxidizing agents. Attacks some plastics, rubber and some coatings.High-temperature chlorination of propylene was allyl chloride by washing, separation, and then by low-temperature chlorination, fractionation, that was finished.
Toxicity Data With Reference
| 1. | skn-rbt 700 mg open MLD | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 3/20 ,1973. | ||
| 2. | eye-rbt 140 mg SEV | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 3/20 ,1973. | ||
| 3. | mmo-sat 100 nmol/plate | ENMUDM Environmental Mutagenesis. 2 (1980),59. | ||
| 4. | mma-sat 500 ng/plate | ENMUDM Environmental Mutagenesis. 7 (Suppl 3)(1985),15. | ||
| 5. | orl-rat LD50:320 mg/kg | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 3/20 ,1973. | ||
| 6. | ihl-rat LCLo:1000 ppm/4H | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
| 7. | ihl-mus LC50:3400 mg/m3/2H | 85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,114. | ||
| 8. | orl-dog LDLo:200 mg/kg | AJHYA2 American Journal of Hygiene. 16 (1932),325. | ||
| 9. | skn-rbt LD50:1770 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. |
Consensus Reports
NTP 10th Report on Carcinogens. Reported in EPA TSCA Inventory.
Safety Profile
Confirmed carcinogen. Poison by ingestion. Moderately toxic by inhalation and skin contact. Experimental reproductive effects. A skin and severe eye irritant. Mutation data reported. Moderately flammable by heat, flames (sparks), or powerful oxidizers. See also ALLYL COMPOUNDS and CHLORINATED HYDROCARBONS, ALIPHATIC. When heated to decomposition it yields highly toxic Cl−. To fight fire, use water (as a blanket), spray, mist, dry chemical.Safety information of 1,2,3-Trichloropropane (96-18-4):
Hazard Codes .gif){kind=small}
T,.gif)
F
Risk Statements
45 May cause cancer
60 May impair fertility
20/21/22 Harmful by inhalation, in contact with skin and if swallowed
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
11 Highly Flammable
38 Irritating to the skin
Safety Statements
53 Avoid exposure - obtain special instruction before use
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37 Wear suitable protective clothing and gloves
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
RTECS TZ9275000
HazardClass 6.1
PackingGroup III
HS Code 29031980
Standards and Recommendations
OSHA PEL: TWA 10 ppm
ACGIH TLV: TWA 10 ppm (skin); Animal Carcinogen
DFG MAK: Confirmed Animal Carcinogen, Suspected Human Carcinogen
Analytical Methods
For occupational chemical analysis use NIOSH: Hydrocarbons, Halogenated, 1003.