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Basic Information
CAS No.: 99-42-3
Name: Benzoic acid,4-hydroxy-3-nitro-, methyl ester
Article Data: 46
Molecular Structure:
Molecular Structure of 99-42-3 (Benzoic acid,4-hydroxy-3-nitro-, methyl ester)
Formula: C8H7NO5
Molecular Weight: 197.147
Synonyms: 3-Nitro-4-hydroxybenzoicacid methyl ester;4-(Methoxycarbonyl)-2-nitrophenol;4-Hydroxy-3-nitrobenzoicacid methyl ester;Methyl4-hydroxy-3-nitrobenzoate;NSC 28667;
EINECS: 202-755-3
Density: 1.432 g/cm3
Melting Point: 74-76 °C
Boiling Point: 311.1 °C at 760 mmHg
Flash Point: 141.9 °C
Hazard Symbols: R36/37/38:Irritating to eyes, respiratory system and skin.;
Risk Codes: 36/37/38
Safety: 26-36/37/39
PSA: 92.35000
LogP: 1.61020
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Chemistry

IUPAC: Methyl 4-hydroxy-3-nitrobenzoate .
Molecular Formula: C8H7NO5
Molecular Weight: 197.14g/mol 
Melting Point: 74-76 oC
Index of Refraction: 1.59
Molar Refractivity: 46.45 cm3
Molar Volume: 137.5 cm3
Polarizability: 18.41×10-24cm3
Surface Tension: 59.7 dyne/cm
Density: 1.432 g/cm3
Flash Point: 141.9 oC
Enthalpy of Vaporization: 57.4 kJ/mol
Boiling Point: 311.1 oC at 760 mmHg
Vapour Pressure: 0.000315 mmHg at 25 oC 
The synonyms of 4-Hydroxy-3-nitrobenzoic acid methyl ester (99-42-3) are 4-Hydroxy-3-nitro-benzoicacimethylester ; Benzoic acid, 4-hydroxy-3-nitro-, methyl ester ; Methyl 4-hydroxy-3-nitrobenzoate ; Methyl-4-hydroxy-3-nitrobenzoic acid ; Methyl 3-nitro-4-hydroxybenzoate ; Methyl 3-nitro-4-hydroxy toluate ; Aurora 6897 .
The structure of 4-Hydroxy-3-nitrobenzoic acid methyl ester (99-42-3) is
. 

Toxicity Data With Reference

1.    

orl-rat LDLo:2500 mg/kg

     EPASR*    United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EHQ-0287-0657S .
2.    

skn-rat LD50:>2 g/kg

     EPASR*    United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EHQ-0287-0657S .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion. Slightly toxic by contact. When heated to decomposition it emits toxic vapors of NOx.
Risk Statements: 36/37/38
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 26-36/37/39
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RTECS: DH2528400.