101854-82-4

• 

• Basic information

  1. Product Name: Methanone, (4-methylphenyl)[(2R,3S)-3-phenyl-2-aziridinyl]-, rel-
  2. Synonyms:
  3. CAS NO:101854-82-4
  4. Molecular Formula: C16H15NO
  5. Molecular Weight: 237.301
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 101854-82-4.mol
  9. Article Data: 5

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: N/A
  3. Flash Point: N/A
  4. Appearance: N/A
  5. Density: N/A
  6. Refractive Index: N/A
  7. Storage Temp.: N/A
  8. Solubility: N/A
  9. CAS DataBase Reference: Methanone, (4-methylphenyl)[(2R,3S)-3-phenyl-2-aziridinyl]-, rel-(CAS DataBase Reference)
  10. NIST Chemistry Reference: Methanone, (4-methylphenyl)[(2R,3S)-3-phenyl-2-aziridinyl]-, rel-(101854-82-4)
  11. EPA Substance Registry System: Methanone, (4-methylphenyl)[(2R,3S)-3-phenyl-2-aziridinyl]-, rel-(101854-82-4)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 101854-82-4(Hazardous Substances Data)

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101854-82-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 101854-82-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,1,8,5 and 4 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 101854-82:
(8*1)+(7*0)+(6*1)+(5*8)+(4*5)+(3*4)+(2*8)+(1*2)=104
104 % 10 = 4
So 101854-82-4 is a valid CAS Registry Number.

101854-82-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name	(+/-)-((2S,3R)-3-phenylaziridin-2-yl)(p-tolyl)methanone

1.2 Other means of identification

Product number	-
Other names	(trans-3-phenyl-aziridin-2-yl)-p-tolyl ketone

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:101854-82-4 SDS

101854-82-4Upstream product

• 122-00-9 para-methylacetophenone 
• 100-52-7 benzaldehyde 
• 121-39-1 ethyl 3-phenylglycidate 
• 14802-30-3 (E)-1-(4-methylphenyl)-3-phenyl-2-propen-1-one 
• 624-31-7 4-tolyl iodide 
• 101854-97-1 3-methoxyamino-3-phenyl-1-p-tolyl-propan-1-one 
• 124-41-4 sodium methylate 

101854-82-4Downstream Products

• 109831-00-7 (2R,3S)-2-(4-Methyl-benzoyl)-3-phenyl-aziridine-1-carboxylic acid phenylamide 
• 128730-68-7 4-Fluoro-N-[(2R,3S)-2-(4-methyl-benzoyl)-3-phenyl-aziridine-1-carbothioyl]-benzamide 
• 128730-69-8 4-Bromo-N-[(2R,3S)-2-(4-methyl-benzoyl)-3-phenyl-aziridine-1-carbothioyl]-benzamide 

101854-82-4Relevant articles and documents

Preparation and reactivity of versatile α-amino ketones

Yu, Lily,Kokai, Akos,Yudin, Andrei K.

, p. 1737 - 1741 (2007)

Many challenges of chemoselectivity arise from the requirement to manipulate incompatible functional groups. Synthetic methods that do not rely on protecting groups are of strategic significance to chemical synthesis. Particularly valuable are molecules w

Amine-promoted, organocatalytic aziridination of enones

Armstrong, Alan,Baxter, Carl A.,Lamont, Scott G.,Pape, Andrew R.,Wincewicz, Richard

, p. 351 - 353 (2007/10/03)

(Chemical Equation Presented) A novel method is presented using N-N ylides (prepared by in situ amination of a tertiary amine) for the aziridination of a range of enone systems. The amine may be used sub-stoichiometrically, and promising levels of enantioselectivity are observed with quinine as promoter.

Spektroskopische Untersuchungen an trans-Chalkonaziridinen

Weber, Fritz Gerd,Liepert, Harald

, p. 175 - 176 (2007/10/02)

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