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10335-68-9

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10335-68-9 Usage

General Description

N-hydroxydodecanamide is a chemical compound that belongs to the class of amides, which are organic compounds derived from carboxylic acids. It is also an N-hydroxy compound, meaning it contains a hydroxyl group directly bonded to the nitrogen atom. N-hydroxydodecanaMide is commonly used as an intermediate in the production of surfactants, lubricants, and other industrial chemicals. N-hydroxydodecanamide has potential applications in various fields, including pharmaceuticals, cosmetics, and polymer synthesis. It is known for its ability to enhance the lubricity and anti-static properties of materials, making it a valuable additive in many industrial processes. Additionally, its hydroxyl group can also make it useful in organic synthesis as a reactive intermediate. Overall, N-hydroxydodecanamide plays a vital role in the development of a wide range of commercial products and technologies.

Check Digit Verification of cas no

The CAS Registry Mumber 10335-68-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,3,3 and 5 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 10335-68:
(7*1)+(6*0)+(5*3)+(4*3)+(3*5)+(2*6)+(1*8)=69
69 % 10 = 9
So 10335-68-9 is a valid CAS Registry Number.

10335-68-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name N-hydroxydodecanamide

1.2 Other means of identification

Product number -
Other names Laurinhydroxamsaeure

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10335-68-9 SDS

10335-68-9Relevant articles and documents

Studies of Collectors. IX. The Flotation of a Trace Amount of Uranium by Using 2-(Alkylamino)propionohydroxamic Acid and Cotelomer-Type Surfactants Bearing Hydroxyaminocarbonyl and Pyridyl Groups

Koide, Yoshifumi,Uchino, Masazumi,Yamada, Kimiho

, p. 3477 - 3484 (1987)

Chelating surfactants bearing hydroxyaminocarbonyl and amino groups (RnAHx) and cotelomer-type surfactants bearing hydroxyaminocarbonyl and pyridyl groups (Ls-VP-Q-Hx) were prepared and applied as flotation collectors for a trace amount of uranium.The uranium in an aqueous of pH 4-8 and in seawater was floated more effectively by ion flotation using RnAHx or by foam fractionation using Ls-VP-Q-Hx, compared with alkylhydroxamic acid (RnHx) and telomers bearing hydroxyaminocarbonyl groups (Lo-Hx).The effective floation was concluded to be due to the chelate effects between the two groups on the complex formation and to the HLB of the resulting complex.Furthermore, the uranium recoveries were examined by using a hydroxamic acid polymer (62Hx), a N-methylhydroxamic acid telomer (Ls5.6MHx), and its cotelomer (Ls3.2VP4.5MHx).

Racemization free longer N-terminal peptide hydroxamate synthesis on solid support using ethyl 2-(tert-butoxycarbonyloxyimino)-2-cyanoacetate

Manne, Srinivasa Rao,Thalluri, Kishore,Giri, Rajat Subhra,Paul, Ashim,Mandal, Bhubaneswar

, p. 6108 - 6111 (2015)

A facile, efficient, racemization-free, and environment friendly protocol for the synthesis of peptide hydroxamic acids directly from carboxylic/amino acids by ethyl 2-(tert-butoxycarbonyloxyimino)-2-cyanoacetate in the presence of DIPEA/DMAP at room temperature is described. The compatibility of this method with Fmoc based solid phase peptide synthesis (SPPS) is also demonstrated by synthesizing three relatively large N-terminal peptide hydroxamic acids on resin. Also, some biologically important hydroxamates are synthesized using this protocol.

Thioether-Directed NiH-Catalyzed Remote γ-C(sp3)-H Hydroamidation of Alkenes by 1,4,2-Dioxazol-5-ones

Chen, Qishu,Du, Bingnan,Ouyang, Yuxin,Yu, Wing-Yiu

supporting information, p. 14962 - 14968 (2021/09/29)

A NiH-catalyzed thioether-directed cyclometalation strategy is developed to enable remote methylene C-H bond amidation of unactivated alkenes. Due to the preference for five-membered nickelacycle formation, the chain-walking isomerization initiated by the NiH insertion to an alkene can be terminated at the γ-methylene site remote from the alkene moiety. By employing 2,9-dibutyl-1,10-phenanthroline as the ligand and dioxazolones as the reagent, the amidation occurs at the γ-C(sp3)-H bonds to afford the amide products in up to 90% yield (>40 examples) with remarkable regioselectivity (up to 24:1 rr).

Ethyl 2-cyano-2-(4-nitrophenylsulfonyloxyimino)acetate-mediated lossen rearrangement: Single-pot racemization-free synthesis of hydroxamic acids and ureas from carboxylic acids

Thalluri, Kishore,Manne, Srinivasa Rao,Dev, Dharm,Mandal, Bhubaneswar

, p. 3765 - 3775 (2014/05/20)

Ethyl 2-cyano-2-(4-nitrophenylsulfonyloxyimino)acetate (4-NBsOXY) mediated Lossen rearrangement and its application for the synthesis of ureas is demonstrated. Required hydroxamic acids for the Lossen rearrangements were synthesized from carboxylic acids using the same reagent. Finally, reaction of an amine with the produced isocyanate resulted in urea. Good yields without racemization were achieved under milder and simpler reaction conditions. Reactions are compatible with common N-protecting groups, such as Boc, Fmoc, Cbz, and benzyl, as well as various OH protecting groups, such as tBu and Bzl. Conversion from carboxylic acid to urea is achieved in one pot. Most importantly, byproducts Oxyma [ethyl 2-cyano-2-(hydroxyimino)acetate] and 4-nitrobenzenesulfonic acid can be recovered easily and can be recycled to prepare the reagent. Thus, the method is environmentally friendly and cost-effective.

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