104282-19-1Relevant articles and documents
Photochemistry of 2-(Trifluoromethyl)cyclohexanone
Semisch, Christoph,Margaretha, Paul
, p. 664 - 668 (1984)
The photochemical behaviour of the title compound 1a is compared to that of the non-fluorinated parent ketone 2-methylcyclohexanone (1b).Substitution of the CH3-group on C(2) by a trifluoromethyl group strongly enhances 2H- and RH-reduction product formation in cyclohexane or 2-propanol and oxetane formation in the presence of 2-methylpropene as olefinic component.Under all these conditions 1b exclusively undergoes α-cleavage, a process observed for 1a only in non-reducing solvents as benzene or tert-butyl alcohol.
Facile and selective alkylation of 3,3,3-trifluoropropene oxide (TFPO) with organoaluminum reagents via pentacoordinate trialkylaluminum complexes
Ooi, Takashi,Furuya, Mayumi,Maruoka, Keiji
, p. 817 - 818 (2007/10/03)
A new organoaluminum-promoted selective alkylation of 3,3,3-trifluoropropene oxide (TFPO) with several nucleophiles has been developed which involves the chelation-activated addition to fluoro epoxides via pentacoordinate trialkylaluminum complexes.
Trifluoromethyl derivatives of cyclohexanol and cyclohexanone and their reactions
Zalesskaya, I. M.,Blakitnyi, A. N.,Saenko, E. P.,Fialkov, Yu. A.,Yagupol'skii, L. M.
, p. 1031 - 1038 (2007/10/02)
The catalytic hydrogenation of mono- and bistrifluoromethylphenols was investigated, and the structure of the obtained trifluoromethylcyclohexanols was established.Methods were developed for the production of trifluoromethyl derivatives of caprolactam and adipic acid.