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10489-97-1

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10489-97-1 Usage

General Description

1,1-Dibromocyclohexane is a chemical compound with the molecular formula C6H10Br2. It is a colorless liquid with a pungent odor. It is primarily used as an intermediate in the synthesis of other organic compounds and as a solvent in chemical processes. 1,1-Dibromocyclohexane is a highly reactive compound and is known to be toxic to aquatic organisms. It is also a suspected environmental toxin, posing potential risks to the environment and human health. The compound has a variety of industrial applications, but it is important to handle it with care and ensure proper disposal to avoid environmental contamination.

Check Digit Verification of cas no

The CAS Registry Mumber 10489-97-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,4,8 and 9 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 10489-97:
(7*1)+(6*0)+(5*4)+(4*8)+(3*9)+(2*9)+(1*7)=111
111 % 10 = 1
So 10489-97-1 is a valid CAS Registry Number.

10489-97-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,1-dibromocyclohexane

1.2 Other means of identification

Product number -
Other names 1,1-dibromo-cyclohexane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10489-97-1 SDS

10489-97-1Relevant articles and documents

The functionalization of saturated hydrocarbons. Part 23. Gif-type bromination and chlorination of saturated hydrocarbons: A non-radical reaction

Barton, Derek H. R.,Csuhai, Eva,Doller, Dario

, p. 9195 - 9206 (1992)

The bromination of saturated hydrocarbons was studied in the GoAggIII system using CBrCl3 and other polyhaloalkanes. This bromination reaction was compared to free radical processes by (i) evaluating the rates of reactions for a series of polyhaloalkanes, by (ii) measuring the selectivity of the different systems towards various saturated hydrocarbons and by (iii) analyzing the product distribution arising from the bromination of cyclohexyl bromide under both the GoAggIII type conditions and from known processes for alkyl radical generation. Some chlorine containing reagents were also examined for C - Cl bond formation in the GoAggIII system. All the experimental findings support a mechanism for the reaction that is different from one involving free radicals. This non-radical pathway is common in all Gif-type systems, as seen in common patterns of selectivity, conditions is in agreement with a non-radical reaction pathway for the Gif-type bromination and chlorination reactions.

The functionalization of saturated hydrocarbons. Part 25. Ionic substitution reactions in GoAggIV chemistry: The formation of carbon-halogen bonds

Barton, Derek H. R.,Beviere, Stephane D.,Chavasiri, Warinthorn

, p. 31 - 46 (2007/10/02)

GoAggIV chemistry (Fe (III) species, tert-butyl hydroperoxide in a mixture of pyridine and acetic acid) in the presence of LiCl can transform saturated hydrocarbons efficiently into the corresponding alkyl chlorides. The transformation into monosubstituted alkyl derivatives by "ionic trapping" reagents arising from the interception of the first intermediate of the system supports the presence of a high valent VFe-C species. Mechanistic studies suggest a possible pathway operating via an Fe-centered ligand coupling. In addition, the production of alkyl chlorides and alkyl bromides could also be achieved employing this system in the presence of halogenating reagents such as CCl4 and BrCCl3.

Dibromocarbonyl Ylides. Deoxygenation of Aldehydes and Ketones by Dibromocarbene

Huan, Zhenwei,Landgrebe, John A.,Peterson, Kimberly

, p. 4519 - 4523 (2007/10/02)

The reaction of phenyl(tribromomethyl)mercury (4) with benzaldehyde-α-13C results in benzal-α-13C bromide and CO.The generality of this deoxygenation was shown by treatment of other aldehydes and ketones with mercurial 4 (1.8:1, benzene, 80 deg C, 4 h): , Ph (46), Et (35), i-Pr (39), t-Bu (19); Ph, Ph (6), Ph, Me (15), Me, Me (16), Et, n-Bu (19), Me, c-C3H5 (20), c-C3H5, c-C3H5 (20), cyclohexanone (38), cyclopentanone (19), norcamphor (46).Additional products in selected cases include (for acetophenone) α-bromostyrene, (for cyclohexanone) 1-bromocyclohexene and 1,1-dibromocyclohexane, (for norcamphor) 2,2-dibromonorbornane, 1,2-dibromonorbornane, 2-bromo-2-norbornene and 1-bromonorbornene, and (for pivaldehyde) 1,1-dibromo-2,2-dimethylpropane.The yields of CO from the treatment of a series of benzaldehydes with mercurial 4 (1.8:1 benzene, 80 deg C, 20 h) are given in parentheses: ArCHO (percent CO), 4-MeO (81), 4-Me (61), 3-Me (55), H (50), 4-F (46), 3-MeO (58), 4-Cl (46), 4-Br (47), 3-Cl (34), 3,4-Cl2 (27).A Hammett-type correlation of log (yield)/(yield)0 vs. ? gave ρ = -0.50 (r = 0.94).

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