105909-88-4Relevant articles and documents
Metal-free desilylative C-C bond formation by visible-light photoredox catalysis
Uygur, Mustafa,Danelzik, Tobias,García Manche?o, Olga
supporting information, p. 2980 - 2983 (2019/03/26)
A newly developed methodology for the use of organosilanes as radical precursors under metal-free and visible-light conditions is presented. The strong oxidant character of the 9-mesityl-10-methylacridinium salt in its excited state enables the transforma
Decatungstate as photoredox catalyst: Benzylation of electron-poor olefins
Montanaro, Sara,Ravelli, Davide,Merli, Daniele,Fagnoni, Maurizio,Albini, Angelo
supporting information; experimental part, p. 4218 - 4221 (2012/09/22)
Excited tetrabutylammonium decatungstate (TBADT), known to activate a variety of compounds via hydrogen atom transfer (HAT), has now been applied as a photoredox catalyst for the effective oxidative cleavage of benzyl silanes and radical benzylation of reducible olefins occurring in isolated yields from poor to excellent.