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10599-59-4

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10599-59-4 Usage

Synthesis Reference(s)

Tetrahedron Letters, 16, p. 627, 1975 DOI: 10.1016/S0040-4039(00)71938-1

Check Digit Verification of cas no

The CAS Registry Mumber 10599-59-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,5,9 and 9 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 10599-59:
(7*1)+(6*0)+(5*5)+(4*9)+(3*9)+(2*5)+(1*9)=114
114 % 10 = 4
So 10599-59-4 is a valid CAS Registry Number.
InChI:InChI=1/C7H10O/c1-6(2)7-4-3-5-8-7/h3-6H,1-2H3

10599-59-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Isopropylfuran

1.2 Other means of identification

Product number -
Other names 2-propan-2-ylfuran

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10599-59-4 SDS

10599-59-4Relevant articles and documents

UNEXPECTED REGIOSELECTIVE DIELS-ALDER CYCLOADDITION REACTIONS BETWEEN 3-FLUOROBENZYNE AND 2-ALKYLFURANS

Gribble, Gordon W.,Keavy, Daniel J.,Branz, Stephen E.,Kelly, William J.,Pals, Mark A.

, p. 6227 - 6230 (1988)

The Diels-Alder reaction between 3-fluorobenzyne (1) and 2-alkylfurans (2) gives a mixture of syn adduct 3 and anti adduct 4.The syn cycloadduct invariably predominates and the regioselectivity increases in the order: R= Me Et i-Pr t-Bu, to a maximum of 90percent syn adduct 3d for 2-tert-butylfuran.These results are rationalized in terms of a concerted nonsynchronous transition state that reflects an alkyl steric effect and a polarized aryne 1.

Activation of sp3 and sp2 C-H bonds of oxygen containing heterocyclic molecules for alkylation and arylation reactions catalyzed by an iron complex

Gartia, Yashraj,Ramidi, Punnamchandar,Cheerla, Sreevishnu,Felton, Charlette M.,Jones, Darin E.,Das, Bhaskar C.,Ghosh, Anindya

, p. 253 - 259 (2014/07/07)

Activation of both sp3 and sp2 CH bonds is reported using an efficient iron(III) complex (1) of a ligand (N2,N6-bis(2,6- diisopropylphenyl)pyridine-2,6-dicarboxamide: L). The iron(III) complex showed catalytic activity of CC coupling reaction of oxygen containing heterocycles, e.g. tetrahydrofuran (THF), with various alkyl, allyl and aryl Grignard reagents under ambient reaction conditions. Complex 1 demonstrated excellent activity and reactions were completed within 30 min to 1 h. A high turnover frequency (TOF) of 1700 h-1 using a low catalyst loading of 0.02 mol% was obtained for the reaction. Interestingly, the catalyst was selective in activation of the CH bond adjacent to the oxygen in various oxygen containing heterocyclic molecules to yield 2-substitituted products.

Eine kurze und hoch stereoselektive Synthese des 1,10-seco-Eudesmanolids Ivangulin

Metz, Peter,Stoelting, Joern,Laege, Mechtild,Krebs, Bernt

, p. 2275 - 2276 (2007/10/02)

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