106268-98-8Relevant articles and documents
Air-stable bifunctional allylation reagents for the asymmetric synthesis of differentiated syn- and anti-1,3-diols
Lee, Jae Seung,Kim, Dongeun,Kong, Suk Bin,Han, Hyunsoo
, p. 4135 - 4139 (2013)
Turning the diols: Enantiomerically pure bifunctional reagents I and ent-I undergo asymmetric aldehyde allylation followed by IrI-catalyzed enantioselective decarboxylative allylic etherification to give differentiated syn- and anti-1,3-diols with complete control of the absolute and relative stereochemistry (see scheme; PMP=para-methoxyphenyl, dbcot=dibenzo[a,e] cyclooctatetraene, DBU=1,8-diazabicyclo[5.4.0]undec-7-ene). Copyright
Concise asymmetric synthesis of orthogonally protected syn - And anti -1,3-aminoalcohols
Lee, Jae Seung,Kim, Dongeun,Lozano, Lucia,Kong, Suk Bin,Han, Hyunsoo
, p. 554 - 557 (2013/04/23)
Novel chiral binfunctional reagents V and ent-V undergo asymmetric aldehyde allylation followed by Ir(I)-catalyzed enantioselective allylic amidation to give orthogonally protected syn- and anti-1,3-aminoalcohols with complete control of absolute and rela
Indole diterpene synthetic studies. 8. The total synthesis of (+)-paspalicine and (+)-paspalinine
Smith III, Amos B.,Kingery-Wood, Jill,Leenay, Tamara L.,Nolen, Ernest G.,Sunazuka, Toshiaki
, p. 1438 - 1449 (2007/10/02)
The development of a unified synthetic strategy for the indole diterpene tremorgens has led to the first total synthesis of (+)-paspalicine (2) and (+)-paspalinine (3), in 22 and 23 steps, respectively. The cornerstone of the approach is the intermediacy
