106750-00-9

• 

• Basic information

  1. Product Name: differolide
  2. Synonyms: differolide;trans-4-(2,5-Dihydro-2-oxo-3-furanyl)-3a,4,5,6-tetrahydro-1(3H)-isobenzofuranone
  3. CAS NO:106750-00-9
  4. Molecular Formula: C12H12O4
  5. Molecular Weight: 220.22128
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 106750-00-9.mol
  9. Article Data: 2

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 526.1°Cat760mmHg
  3. Flash Point: 288.6°C
  4. Appearance: /
  5. Density: 1.33g/cm³
  6. Vapor Pressure: 3.69E-11mmHg at 25°C
  7. Refractive Index: 1.575
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. CAS DataBase Reference: differolide(CAS DataBase Reference)
  11. NIST Chemistry Reference: differolide(106750-00-9)
  12. EPA Substance Registry System: differolide(106750-00-9)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 106750-00-9(Hazardous Substances Data)

• Suppliers
• Usage
• SDS
• Upstream product
• Downstream Products
• Article

106750-00-9 Suppliers

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• differolide

  Cas No: 106750-00-9

• USD $ 9.0-99.0 / Kilogram

• 1 Kilogram

• 1 Kilogram/Month

• Hebei Nengqian Chemical Import and Export Co., LTD
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• Differolide

  Cas No: 106750-00-9

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• Henan Allgreen Chemical Co.,Ltd
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• (3aR,4R)-4-(5-oxo-2H-furan-4-yl)-3a,4,5,6-tetrahydro-3H-2-benzofuran-1-one

  Cas No: 106750-00-9

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• BOC Sciences
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• Differolide

  Cas No: 106750-00-9

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106750-00-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 106750-00-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,6,7,5 and 0 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 106750-00:
(8*1)+(7*0)+(6*6)+(5*7)+(4*5)+(3*0)+(2*0)+(1*0)=99
99 % 10 = 9
So 106750-00-9 is a valid CAS Registry Number.

InChI:InChI=1/C12H12O4/c13-11-9(4-5-15-11)7-2-1-3-8-10(7)6-16-12(8)14/h3-4,7,10H,1-2,5-6H2/t7-,10+/m0/s1

106750-00-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name	(3aR,4R)-4-(5-oxo-2H-furan-4-yl)-3a,4,5,6-tetrahydro-3H-2-benzofuran-1-one

1.2 Other means of identification

Product number	-
Other names	Differolide

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:106750-00-9 SDS

106750-00-9Upstream product

• 238433-82-4 3-vinyl-2(5H)-furanone 
• 151062-71-4 Methyl (1'S,2'R,3'R,4'S)-(+)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate 
• 151062-74-7 (+)-3-<(1'R,2'R)-2'-Hydroxymethyl-3'-formyl-3'-cyclohexenyl>-2(5H)-furanone 
• 151062-75-8 (5R,6R)-(+)-5-(2',5'-Dihydro-2'-oxo-3'-furanyl)-6-hydroxymethyl-1-cyclohexene-1-carboxylic Acid 
• 150989-84-7 Methyl(1'R,2'S,3'S,4'R)-(-)-2',3'-Bis(benzyloxymethyl)-4'-hydroxycyclohexylacetate 
• 150989-90-5 (-)-3-<(1'S,2'S)-2'-Hydroxymethyl-3'-formyl-3'-cyclohexenyl>-2(5H)-furanone 
• 150989-91-6 (5S,6S)-(-)-5-(2',5'-Dihydro-2'-oxo-3'-furanyl)-6-hydroxymethyl-1-cyclohexene-1-carboxylic Acid 
• 151062-62-3 (1S,2R,6R,7S,9S)-(+)-9-Hydroxy-4-oxatricyclo<5.2.2.0^2,6>undecan-3-one 
• 151062-66-7 (1S,2S,4S,5R,6R)-(+)-5,6-Bis(benzyloxymethyl)bicyclo<2.2.2>octan-2-ol 
• 151062-73-6 (+)-3-<(1'R,2'R)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenyl>-2(5H)-furanone 
• 151062-72-5 Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate 
• 150989-89-2 (-)-3-<(1'S,2'S)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenyl>-2(5H)-furanone 
• 150989-85-8 Methyl (1'R,2'S)-(-)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate 

106750-00-9Downstream Products

106750-00-9Relevant articles and documents

An enyne metathesis/(4 + 2)-dimerization route to (±)-differolide

Hoye, Thomas R.,Donaldson, Scott M.,Vos, Tricia J.

, p. 277 - 279 (1999)

(equation presented) A concise total synthesis of (±)-differolide (1) has been achieved. 2-Vinylbutenolide (2) was prepared by enyne metathesis of allyl propynoate (3) usinq the Grubbs initiator 4. This reaction was examined by 1H NMR spectroscopy, which led to the hypothesis that low concentration of ruthenium species and high concentration of enyne substrate would be advantageous. Accordingly, slow addition of 4 to solutions of enyne 3 was found to be beneficial. Spontaneous dimerization of 2 gave (±)-differolide (1) and an isomer.

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