107244-34-8Relevant articles and documents
Asymmetric total synthesis of (+)-6-epi-castanospermine by the stereoselective formation of a syn,anti acetylenic 2-amino-1,3-diol stereotriad
Louvei, Julien,Botuha, Candice,Chemla, Fabrice,Demont, Emmanuel,Ferreira, Franck,Perez-Luna, Alejandro
experimental part, p. 2921 - 2926 (2010/08/05)
The asymmetric total synthesis of (+)-6-epi-castanospermine (1) is described herein. In this synthesis the diastereoselective addition of a racemic allenylzinc reagent to an enantiopure α-alkoxy-fert-butylsulfinylimine is the key step and is followed by t
Simple Total Syntheses of (+)-Castanospermine and (+)-6-Epicastanospermine Using Indium-Mediated Allylation
Kim, Jin Hyo,Seo, Woo Duck,Lee, Jin Hwan,Lee, Byong Won,Park, Ki Hun
, p. 2473 - 2478 (2007/10/03)
The indium-mediated allylation of α-aminoaldehyde 3 from D-glucono-δ-lactone provided the syn-aminoalcohol with excellent diastereoselectivity. syn-Aminoalcohol was easily applied to the total syntheses of the potent glycosidase inhibitors; (+)-castanospe
Enantioselective total syntheses of (+)-castanospermine, (+)-6- epicastanospermine, (+)-australine, and (+)-3-epiaustraline
Denmark, Scott E.,Martinborough, Esther A.
, p. 3046 - 3056 (2007/10/03)
The total syntheses of the potent glycosidase inhibitors castanospermine ((+)-1), 6-epicastanospermine ((+)-2), australine ((+)-3), and 3- epiaustraline ((+)-4) are described. The syntheses of indolizidine alkaloids (+)-1 and (+)-2 were accomplished in ei
