107804-96-6Relevant articles and documents
Rhodium-catalyzed hydroformylation of cyclopropenes
Sherrill, William M.,Rubin, Michael
supporting information; experimental part, p. 13804 - 13809 (2009/02/06)
The first catalytic diastereo- and enantioselective hydroformylation of cyclopropenes was demonstrated. The reaction proceeds efficiently under very mild conditions and low catalyst loadings providing high yields of cyclopropylcarboxaldehydes. This novel methodology represents a convenient, atom-economic approach toward optically active cyclopropylcarboxaldehydes from readily available prochiral cyclopropenes.