111299-29-7Relevant articles and documents
One-pot synthesis of α,β-epoxy ketones by palladium-catalyzed epoxidation-oxidation of terminal allylic alcohols
Singh, Fateh V.,Pena, Jesus M.,Stefani, Hélio A.
experimental part, p. 1671 - 1673 (2010/05/19)
Described herein is a one-pot synthesis of α,β-epoxy ketones using a palladium-catalyzed epoxidation-oxidation sequence. Functionalized terminal allylic alcohols are treated with m-CPBA under mild reaction conditions to obtain the α,β-epoxy ketones. The m