1119-64-8

• 

• Basic information

  1. Product Name: 1-bromohex-1-yne
  2. Synonyms: 1-Bromohex-1-yne; 1-hexyne, 1-bromo-
  3. CAS NO:1119-64-8
  4. Molecular Formula: C₆H₉Br
  5. Molecular Weight: 161.0397
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 1119-64-8.mol
  9. Article Data: 1

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 153.9°C at 760 mmHg
  3. Flash Point: 49.9°C
  4. Appearance: N/A
  5. Density: 1.298g/cm³
  6. Vapor Pressure: 4.19mmHg at 25°C
  7. Refractive Index: 1.485
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. CAS DataBase Reference: 1-bromohex-1-yne(CAS DataBase Reference)
  11. NIST Chemistry Reference: 1-bromohex-1-yne(1119-64-8)
  12. EPA Substance Registry System: 1-bromohex-1-yne(1119-64-8)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 1119-64-8(Hazardous Substances Data)

• Suppliers
• Usage
• SDS
• Upstream product
• Downstream Products
• Article

1119-64-8 Suppliers

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• 1-Hexyne, 1-bromo-

  Cas No: 1119-64-8

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• Nsc526633 CAS 1119-64-8

  Cas No: 1119-64-8

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• 1-Hexyne, 1-bromo-

  Cas No: 1119-64-8

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• Hangzhou J&H Chemical Co., Ltd.
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• 1-Hexyne, 1-bromo- cas 1119-64-8

  Cas No: 1119-64-8

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1119-64-8 Usage

Type of compound

brominated alkyne

Structural features

contains a carbon-carbon triple bond and a bromine atom attached to one of the carbon atoms in the chain

Usage

commonly used in organic synthesis as a starting material for various reactions, including coupling and substitution reactions

Application

used as an intermediate in the production of pharmaceuticals, agrochemicals, and other fine chemicals

Physical state

clear, colorless liquid

Odor

strong, pungent

Flammability

flammable

Hazardous nature

hazardous, should be handled with care

Storage

should be stored in a cool, well-ventilated area

Check Digit Verification of cas no

The CAS Registry Mumber 1119-64-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,1 and 9 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1119-64:
(6*1)+(5*1)+(4*1)+(3*9)+(2*6)+(1*4)=58
58 % 10 = 8
So 1119-64-8 is a valid CAS Registry Number.

1119-64-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name	1-bromohex-1-yne

1.2 Other means of identification

Product number	-
Other names	1-Bromohexyne

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1119-64-8 SDS

1119-64-8Upstream product

• 1375484-94-8 [Bu₄N][C₄H₉CCBF₃] 

1119-64-8Downstream Products

• 62217-45-2 1-phenylocta-1,3-diyne 
• 101276-98-6 acetic acid-(1-octa-1,3-diynyl-cyclohexyl ester) 
• 39546-85-5 8-methyl-undec-5t-ene 
• 39546-82-2 1-Methyl-4-pentylidene-cyclohexane 
• 32753-85-8 2-Benzylamino-deca-3,5-diyn-1-ol 
• 67532-05-2 (Z)-1-bromo-1-cyclohexyl-1-hexene 
• 56962-83-5 Dicyclohexyl-((Z)-hex-1-enyl)-borane 
• 16538-48-0 (E)-hex-1-en-1-ylcyclohexane 
• 16695-37-7 (E)-6-Undecen-1-ol 
• 16336-82-6 (E)-5-dodecen-7-yne 
• 28884-88-0 dodec-7-yn-6-one 
• 124-18-5 decane 
• 110-53-2 1-Bromopentane 
• 49677-13-6 (E)-1,2-dibromohex-1-ene 

1119-64-8Relevant articles and documents

Reactions of perfluorinated alkenyl-, alkynyl-, alkyltrifluoroborates, and selected hydrocarbon analogues with the halogenating agents Hal2 (Hal = F, Cl, Br), "brF" (BrF3-Br2 1:1), and ICl

Bardin, Vadim V.,Adonin, Nicolay Yu.,Frohn, Hermann-Josef

, p. 565 - 579 (2012/05/20)

Reactions of [Bu4N][RBF3] [R = CnF 2n+1CF=CF (cis, trans), CF2=CF, CF2=C(CF 3), trans-C4H9CF=CF, trans-C6H 5CF=CF, C4H9CH=CH (cis, trans), CF 3C≡C, and C4H9C≡C] with chlorine, bromine, BrF3 + Br2 (as equivalent of "BrF"), and ICl in solution (CH2Cl2, CHCl3, CF 3CH2CF2CH3) led to 1, 2-addition of halogen and/or replacement of boron by halogen (halodeboration). The reaction of [Bu4N][CF3C≡CBF3] with less than equimolar amounts of diluted fluorine (5 %) in 1, 1, 1, 3, 3-pentafluorobutane (PFB) showed only [Bu4N][CF3CF2CF 2BF3] as fluorine addition product besides extensive fluorodeboration. Suspensions of the insoluble K[CF2=CFBF 3] salt reacted with Cl2 and Br2 in CH 2Cl2 giving preferentially products of halogen addition across the C=C bond. In reactions with ICl iododeboration with formation of CF2=CFI occurred besides 1, 2-addition with formation of [CF 2I-CFClBF3]-. The halodeboration reaction of[Bu4N][trans-C4H9CF=CFBF3] with Br2, "BrF", and ICl, of K[trans-C6H 5CF=CFBF3] with Br2, and of [Bu 4N][trans-C4F9CF=CFBF3] with ICl proceeded stereospecifically. Copyright

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