114693-78-6

• 

• Basic information

  1. Product Name: trimethyl-(2-tert-butyloxiran-2-yl)silane
  2. Synonyms: trimethyl-(2-tert-butyloxiran-2-yl)silane
  3. CAS NO:114693-78-6
  4. Molecular Formula: C9H20OSi
  5. Molecular Weight: 172.34
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 114693-78-6.mol
  9. Article Data: 2

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 169.5°Cat760mmHg
  3. Flash Point: 42.4°C
  4. Appearance: /
  5. Density: 0.85g/cm³
  6. Vapor Pressure: 2.04mmHg at 25°C
  7. Refractive Index: 1.431
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. CAS DataBase Reference: trimethyl-(2-tert-butyloxiran-2-yl)silane(CAS DataBase Reference)
  11. NIST Chemistry Reference: trimethyl-(2-tert-butyloxiran-2-yl)silane(114693-78-6)
  12. EPA Substance Registry System: trimethyl-(2-tert-butyloxiran-2-yl)silane(114693-78-6)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 114693-78-6(Hazardous Substances Data)

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114693-78-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 114693-78-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,6,9 and 3 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 114693-78:
(8*1)+(7*1)+(6*4)+(5*6)+(4*9)+(3*3)+(2*7)+(1*8)=136
136 % 10 = 6
So 114693-78-6 is a valid CAS Registry Number.

InChI:InChI=1/C9H20OSi/c1-8(2,3)9(7-10-9)11(4,5)6/h7H2,1-6H3

114693-78-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name	(2-tert-butyloxiran-2-yl)-trimethylsilane

1.2 Other means of identification

Product number	-
Other names	-

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:114693-78-6 SDS

114693-78-6Upstream product

• 14630-42-3 (3,3-dimethyl-1-butynyl)trimethylsilane 
• 26567-95-3 (Z)-1-(trimethylsilyl)-3,3-dimethyl-1-butene 
• 20107-37-3 ((E)-3,3-Dimethyl-but-1-enyl)-trimethyl-silane 

114693-78-6Downstream Products

114693-78-6Relevant articles and documents

Oxiranyl Anions. Improved Synthesis of Trimethylsilyl-Substituted Oxiranyl Anions and Their Additions to Aldehydes and Ketones

Molander, Gary A.,Mautner, Konrad

, p. 4042 - 4050 (2007/10/02)

Conditions for the metalation of trimethylsilyl-substituted oxiranes have been optimized.Utilizing sec-butyllithium in diethyl ether with tetramethylethylenediamine, oxiranyl anions possessing virtually all substitution patterns are generated in excellent yields.These unique carbanions are stable to α-elimination for periods of hours at -116 deg C.Most of the anions exhibit strict retention of configuration at the metalated carbon stereocenter, although one example displaying configurational inversion has been discovered.Reactions with aldehydes and ketones havebeen explored.Although low diastereoselectivity in reactions with alkyl aldehydes is observed, good to excellent diasterofacial additions to ketone and conjugated aldehydes can be achieved.

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