114968-87-5Relevant articles and documents
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Aidene,Barbot,Miginiac
, p. 117 - 127 (2007/10/03)
A new general synthesis of C-subtituted α-aminoacids is described, using at first the regioselective reaction between α-unsaturated organozincs and N-(phenylsulfanyl)iminoesters.
PALLADIUM-CATALYZED ALLYLATION OF α-ISOCYANOCARBOXYLATES
Ito, Yoshihiko,Sawamura, Masaya,Matsuoka, Masato,Matsumoto, Yonetatsu,Hayashi, Tamio
, p. 4849 - 4852 (2007/10/02)
α-Isocyanocarboxylates underwent palladium-catalyzed allylation with allylic acetates, in which Π-allylpalladium(II)intermediate was involved.The catalytic allylation of methyl α-isocyano(phenyl)acetate using an optically active ferrocenylphosphine ligand