115029-35-1Relevant articles and documents
Chemistry of urea nitro derivatives: IV. Reaction of N,N′ -dinitrourea with formaldehyde
Il'yasov,Lobanova,Popov,Sataev
, p. 1739 - 1743 (2002)
Reaction of N,N′-dinitrourea with formaldehyde, depending on the conditions, leads to formation of various hydroxymethyl derivatives of N-nitroamines and products of their further transformations.
2-nitroguanidine derivatives: X. Synthesis and nitration of 4-nitriminotetrahydro-1,3,5-oxadiazine and 2-nitriminohexahydro-1,3,5-triazine and their substituted derivatives
Metelkina
, p. 1437 - 1440 (2008/09/16)
A new synthetic procedure was developed to obtain 1-hydroxymethyl-2- nitroguanidine from 2-nitroguanidine and formaldehyde without catalyst. Reactions of 2-nitroguanidine and its 1-methyl-and 1-phenylsubstituted derivatives with formaldehyde and urotropin under acid catalysis resulted in 4-nitriminotetrahydro-1,3,5-oxadiazine and 2-nitriminohexahydro-1,3,5-triazine and their methyl-and phenyl-substituted derivatives, whose nitration with concn. HNO3 in the presence of acetic anhydride and concn. H 2SO4 depending on the temperature conditions led to the formation of 4-nitrimino-3,5-dinitrotetrahydro-1,3,5-oxadiazine, 3-methyl-4-nitrimino-5-nitrotetrahydro-1,3,5-oxadiazine, 2-nitrimino-5- nitrohexahydro-1,3,5-triazine, and 1,3,5-trinitro-hexahydro-1,3,5-triazine-2- one.