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115936-18-0

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115936-18-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 115936-18-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,5,9,3 and 6 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 115936-18:
(8*1)+(7*1)+(6*5)+(5*9)+(4*3)+(3*6)+(2*1)+(1*8)=130
130 % 10 = 0
So 115936-18-0 is a valid CAS Registry Number.

115936-18-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name (2S,3S)-anti-2-methyl-1-phenyl-3-hydroxy-1-butanone

1.2 Other means of identification

Product number -
Other names (2S,3S)-3-Hydroxy-2-methyl-1-phenyl-butan-1-one

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:115936-18-0 SDS

115936-18-0Relevant articles and documents

Enantioselective Monoreduction of 2-Alkyl-1,3-diketones Mediated by Chiral Ruthenium Catalysts. Dynamic Kinetic Resolution

Eustache, Florence,Dalko, Peter I.,Cossy, Janine

, p. 1263 - 1265 (2002)

(Matrix Presented) The reduction of 2-alkyl-1,3-diketones using (R,R)- or (S,S)-RuCl[N-(tosyl)-1,2-diphenylethylenediamine](p-cymene) in the presence of formic acid and triethylamine affords syn-2-alkyl-3-hydroxy ketones as the major products with high en

Synthesis of valuable chiral intermediates by isolated ketoreductases: Application in the synthesis of α-alkyl-β-hydroxy ketones and 1,3-diols

Kalaitzakis, Dimitris,Rozzell, J. David,Smonou, Ioulia,Kambourakis, Spiros

, p. 1958 - 1969 (2007/10/03)

Regio- and stereoselective reductions of α-substituted 1,3-diketones to the corresponding β-keto alcohols or 1,3-diols by using commercially available ketoreductases (KREDs) are described. A number of α-monoalkyl- or dialkyl-substituted symmetrical as well as non-symmetrical diketones were reduced in high optical purities and chemical yields, in one or two enzymatic reduction steps. In most cases, two or even three out of the four possible diastereomers of α-alkyl-β-keto alcohols were synthesized by using different enzymes, and in two examples both ketones were reduced to the 1,3-diol. By replacing the α-alkyl substituent with the OAc group, 1-keto-2,3-diols, as well as 1,2,3-triols were synthesized in high optical purities. These enzymatic reactions provide a simple, highly stereoselective and quantitative method for the synthesis of different diastereomers of valuable chiral synthons from non-chiral, easily accessible 1,3-diketones.

Palladium-Catalyzed Asymmetric 1,4-Disilylation of α,β-Unsaturated Ketones: Catalytic Asymmetric Synthesis of β-Hydroxy Ketones

Hayashi, Tamio,Matsumoto, Yonetatsu,Ito, Yoshihiko

, p. 5579 - 5581 (2007/10/02)

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