118824-34-3Relevant articles and documents
Reversible chemoselective transetherification of vinylogous esters using Fe-catalyst under additive free conditions
Parvathalu, Nenavath,Agalave, Sandip G.,Mohanta, Nirmala,Gnanaprakasam, Boopathy
, p. 3258 - 3266 (2019/03/26)
An additive/Br?nsted acid/base free, highly efficient and chemoselective transetherification of electron deficient vinylogous esters and water mediated de-alkylation using an earth-abundant Fe-catalyst under very mild reaction conditions is described. This reaction is highly selective to primary alcohols over secondary alcohols, has good functional group tolerance, is scalable to gram scale and a purification free sequential transetherification in a continuous flow mode is demonstrated.
FACILE SYNTHESIS OF FUNCTIONALISED SPIROETHERS VIA RADICAL CYCLISATIONS
Middleton, Donald S.,Simpkins, Nigel S.,Terrett, Nicholas K.
, p. 1315 - 1318 (2007/10/02)
Alcohols bearing suitable chains for radical initiation are smoothly condensed with cyclic β-diketones to afford systems which undergo radical cyclisation to give various spiroether products.