119065-82-6

• 

• Basic information

  1. Product Name: (1R,2R,3S,7S,7aR)-3-(hydroxymethyl)hexahydro-1H-pyrrolizine-1,2,7-triol
  2. Synonyms:
  3. CAS NO:119065-82-6
  4. Molecular Formula: C₈H₁₅NO₄
  5. Molecular Weight: 189.209
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 119065-82-6.mol
  9. Article Data: 4

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 417.4°C at 760 mmHg
  3. Flash Point: 263.5°C
  4. Appearance: N/A
  5. Density: 1.53g/cm³
  6. Vapor Pressure: 1.03E-08mmHg at 25°C
  7. Refractive Index: 1.647
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. CAS DataBase Reference: (1R,2R,3S,7S,7aR)-3-(hydroxymethyl)hexahydro-1H-pyrrolizine-1,2,7-triol(CAS DataBase Reference)
  11. NIST Chemistry Reference: (1R,2R,3S,7S,7aR)-3-(hydroxymethyl)hexahydro-1H-pyrrolizine-1,2,7-triol(119065-82-6)
  12. EPA Substance Registry System: (1R,2R,3S,7S,7aR)-3-(hydroxymethyl)hexahydro-1H-pyrrolizine-1,2,7-triol(119065-82-6)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 119065-82-6(Hazardous Substances Data)

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• Downstream Products
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119065-82-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 119065-82-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,9,0,6 and 5 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 119065-82:
(8*1)+(7*1)+(6*9)+(5*0)+(4*6)+(3*5)+(2*8)+(1*2)=126
126 % 10 = 6
So 119065-82-6 is a valid CAS Registry Number.

119065-82-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name	(1R,2R,3S,7S,7aR)-3-(hydroxymethyl)hexahydro-1H-pyrrolizine-1,2,7-triol

1.2 Other means of identification

Product number	-
Other names	(1R,2R,3S,7S,7aR)-3-Hydroxymethyl-hexahydro-pyrrolizine-1,2,7-triol

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:119065-82-6 SDS

119065-82-6Upstream product

• 126594-78-3 3-epiaustralien tetraacetate 
• 314057-09-5 N-((2S,3S,4R,5S)-2-Allyl-4,5,6-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-formamide 
• 1204748-41-3 (1S,5S,6R,7R,7aR)-6,7-bis(benzyloxy)-5-((tert-butyldimethylsilyloxy)methyl)hexahydro-1H-pyrrolizin-1-ol 

119065-82-6Downstream Products

119065-82-6Relevant articles and documents

Chemo-enzymatic total synthesis of 3-epiaustraline, australine, and 7-epialexine

Romero,Wong

, p. 8264 - 8268 (2000)

Sequential enzymatic aldol reaction and bis-reductive amination leads to the total syntheses of tetrahydroxylated pyrrolizidine alkaloids, 3-epiaustaline (14), australine (1), and 7-epialexine (11). This approach allows for their rapid construction without the need for protecting group manipulation of the hydroxyl functionality. In addition, an improved procedure for the asymmetric epoxidation of divinyl carbinol (3) was described, and the product was used in a concise synthesis of the required triol 7 and ent-7.

Total synthesis of uniflorine A, casuarine, australine, 3-epi-australine, and 3,7-di-epi-australine from a common precursor

Ritthiwigrom, Thunwadee,Willis, Anthony C.,Pyne, Stephen G.

supporting information; experimental part, p. 815 - 824 (2010/06/15)

(Chemical Equation Presented) Aflexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described. 2009 American Chemical Society.

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